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serg [7]
3 years ago
5

Given the values of ΔGfo given below in kJ/mol, calculate the value of ΔGo in kJ for the combustion of 1 mole of butane to form

carbon dioxide and liquid water. ΔGfo (C4H10(g)) = -17 ΔGfo (CO2(g)) = -395 ΔGfo (H2O(l)) = -238
Chemistry
1 answer:
xz_007 [3.2K]3 years ago
4 0

Answer:

Δ_rG=-2753kJ

Explanation:

Hello,

Butane's combustion is:

C_4H_{10}+\frac{13}{2} O_2-->4CO_2+5H_2O

Now the change in the Gibbs free energy for this reaction is computed via (don't forget that oxygen's Gibbs free energy of formation is 0 since it is an element):

Δ_rG=4Δ_fG_{CO_2}+5Δ_fG_{H_2O}-Δ_fG_{C_4H_{10}}

Δ_rG=4(-395kJ/mol)+5(-238kJ/mol)-(-17kJ/mol)

Δ_rG=-2753kJ/mol

Now, since the calculation is done for 1 mol of butane, the change in the Gibbs free energy for this fuel is:

Δ_rG=-2753kJ

Best regards.

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Oxidation/reduction (redox) reactions like this: 2H2(g) + O2(g) ⇒ 2H2O(l) will occur spontaneously. To make the reaction proceed
igor_vitrenko [27]

The process is called electrolysis.

3 0
3 years ago
Calculate the mass of CaCl2•2H2O required to make 100.0 mL of a 0.100 M solution. Each of the calculations below will take you t
Zolol [24]

Answer:

The mass is 1.4701 grams and the moles is 0.01.

Explanation:

Based on the given question, the volume of the solution is 100 ml or 0.1 L and the molarity of the solution is 0.100 M. The moles of the solute (in the given case calcium chloride dihydride (CaCl2. H2O) can be determined by using the formula,  

Molarity = moles of solute/volume of solution in liters

Now putting the values we get,  

0.100 = moles of solute/0.1000

Moles of solute = 0.100 * 0.1000

= 0.01 moles

The mass of CaCl2.2H2O can be determined by using the formula,  

Moles = mass/molar mass

The molar mass of CaCl2.2H2O is 147.01 gram per mole. Now putting the values we get,  

0.01 = mass / 147.01

Mass = 147.01 * 0.01

= 1.4701 grams.  

4 0
3 years ago
Isobutyl propionate is the substance that provides the flavor for rum extract. combustion of a 1.152 g sample of this carbon-hyd
Ulleksa [173]

Answer;

C7H14O2

Solution;

Isobutyl contains , oxygen, carbon and hydrogen (total mass is 1.152 g)

Mass of carbon = 12/44 × 2.726 g

                           = 0.743455 g

Mass of Hydrogen  = 2/18 × 1.116 g

                            =  0.124 g

Mass of oxygen = 1.152 - (0.7435 + 0.124)

                           =  0.2845 g

Moles of carbon ;  0.7435/12 = 0.06196 moles

Moles of hydrogen; 0.124/1 = 0.124 moles

Moles of oxygen;  0.2845/16 = 0.01778 moles

Ratios ; 0.06196/0.01778 ; 0.124/0.01778 : 0.01778/0.01778

         =  3.5 :  7.0 : 1

To make them whole numbers ; we multiply the ratios by 2  to get;

(3.5 :  7.0 : 1 )2 = 7 : 14 : 2

Thus, the empirical formula of Isobutyl propionate  is C7H14O2


4 0
3 years ago
What is the binding energy of a nucleus that has a mass defect of 5.81*10-^29 kg
IrinaVladis [17]

Answer:

Choice A: Approximately 5.23 \times 10^{-29} joules.

Explanation:

Apply the famous mass-energy equivalence equation to find the energy that correspond to the \rm 5.81\times 10^{-29} kilograms of mass.

E = m \cdot c^{2},

where

  • E stands for energy,
  • m stands for mass, and
  • c is the speed of light in vacuum.

The speed of light in vacuum is a constant. However, finding the right units for this value can simplify the calculations a lot. What should be the unit of c?

The mass given is in the appropriate SI unit:

Mass is in kilograms.

Thus, proceed with the speed of light in SI units. The SI unit for speed is meters per second. For the speed of light, c \approx \rm 3.00\times 10^{8}\;m\cdot s^{-1}.

Apply the mass-energy equivalence:

\begin{aligned} E &= m \cdot c^{2} \\ &= \rm 5.81\times 10^{-29}\; kg \times {\left(3.00\times 10^{8}\; m\cdot s^{-1}\right)}^{2}\\ &\approx \rm 5.23\times 10^{-12}\;kg\cdot m^{2}\cdot s^{-2} \end{aligned}.

The unit of energy is not in joules. Don't be alerted. Consider the definition of a joule of energy. One joule is the work done on an object when a force of one newton acts on the object in the direction of the force through the distance of one meter. (English Wikipedia.)

\rm 1\; J = 1\; N \times 1\; m.

However, a force of one newton is defined as the force required to accelerated an object with a mass of one kilogram (not gram) at a rate of one meter per second squared. (English Wikipedia.)

\begin{aligned}\rm 1\; J &= \rm 1\; N \times 1\; m\\ & = \rm \left(1\; kg\times 1\; m\cdot s^{-2}\right)\times 1\; m\\ &= \rm 1\; kg \cdot m^{2}\cdot s^{-2}\end{aligned}.

In other words, the mass defect here is also \rm 5.23\times 10^{-12}\; J.

7 0
3 years ago
Read 2 more answers
If 37.5 mL of 0.100 M calcium chloride reacts completely with aqueous silver nitrate, what is the mass of AgCl (MM
Travka [436]

Answer:

OPTION C is correct

C) 1.07 g

Explanation:

CaCl2(aq) + 2 AgNO3(aq) → 2 AgCl(s) + Ca(NO3)3(aq)

But we know molarity molarity= number of moles of solute/ volume of the solution

M= n/V

From the equation above

number of moles of Cacl2 = (37.5 ×0 .100 × 10^-3) = 0.00375 moles.

Then

1 mole of Cacl2 yields 2 moles of Agcl2

0.00375 moles of Cacl2 will produce let say Y.

Y= (0.00375 ×2)/1

= 0.0075 moles.

Number of moles of Agcl2 = mass /molar mass of Agcl

Molar mass of Agcl = 178

Then mass = 178 ×0.0075 = 1.047

Therefore, the mass of agcl precipitate is

1.07 g

8 0
3 years ago
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