What can be determined about the electron of an atom
1 answer:
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Answer:
1 .
2.
Explanation:
The more stable the ionic compound, the more is it lattice energy.
- The more the charge on the cation and the anion, the greater is the lattice energy.
- The less the size of the cation and the anion, the greater is the lattice energy.
Scandium oxide () is an oxide in which
behaves as cation and
behaves as anion.
The compounds which has higher lattice energy than scandium oxide are:
1 .
This is because the charge are same on the cation and the anion as in the case of the Scandium oxide but the size of the cation is smaller than
. Thus, this corresponds to higher lattice energy.
2.
This is because the charge on the cation is greater than that of
and also the size of the cation
is smaller than
. Thus, this corresponds to higher lattice energy.
Answer:
Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.
Explanation:
Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.
