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Gelneren [198K]
3 years ago
7

10. Isolation of a pure sample of the third product, which has been determined to be an isomer of the major and minor products,

gives the following 13C NMR data. Determine the structure of this product. 2 points

Chemistry
1 answer:
Ymorist [56]3 years ago
7 0

Answer:

Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.

Explanation:

Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.

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Rate = K[A]
Aleks [24]

Answer:

9 × 10⁻³ mol·L⁻¹s⁻¹  

Explanation:

Data:

  k = 1 × 10⁻³ L·mol⁻¹s⁻¹

[A] = 3 mol·L⁻¹

Calculation:

rate = k[A]² = 1 × 10⁻³ L·mol⁻¹s⁻¹ × (3 mol·L⁻¹)² = 9 × 10⁻³ mol·L⁻¹s⁻¹

8 0
3 years ago
For each reaction, identify the element that gets reduced and the element that gets oxidized. 2 AgCl + Zn ⟶ 2 Ag + ZnCl 2 2AgCl+
Mnenie [13.5K]

Answer:

Explanation:

Oxidation:

Oxidation involve the removal of electrons and oxidation state of atom of an element is increased.

Reduction:

Reduction involve the gain of electron and oxidation number is decreased.

Oxidizing agents:

Oxidizing agents oxidize the other elements and itself gets reduced.

Reducing agents:

Reducing agents reduced the other element are it self gets oxidized.

Consider the following reaction:

2AgCl + Zn  → 2Ag + ZnCl₂

In this reaction oxidation state of Zn on left side is 0 while on right side +2 so it gets oxidized and oxidation state of Ag on left side is +1 and on right side 0 so it get reduced.

4NH₃  +  3O₂   →   2N₂ +  6H₂O

In this reaction oxidation state of nitrogen on left side is -3 while on right side 0 so it gets oxidized and oxidation state of oxygen on left side is 0 and on right side -2 so it get reduced.

Fe₂O₃ +  2Al  →   Al₂O₃ +  2Fe

In this reaction oxidation state of iron on left side is +3 while on right side 0 so it gets reduced and oxidation state of Al on left side is 0 and on right side +3 so it get oxidized.

4 0
3 years ago
Texture provides clues about how igneous rocks were formed A. true B. False
hammer [34]
A.) true

Because the rocks are formed near lava so the texture would be smooth
3 0
2 years ago
What is the concentration of h+ ions in a 2.20 m solution of hno3?
kvv77 [185]

The question is improperly formatted.

What is the concentration of H+ ions in a 2.2 M solution of HNO3.

Answer:-

2.2 moles of H+ per litre

Explanation:-

M stands for molarity. 2.2 M means 2.2 moles of HNO3 is present per litre of the solution.

Now HNO3 has just 1 H in it's formula. HNO3 would give H+. So 2.2 moles of HNO3 would mean 2.2 moles of H+ per litre.

7 0
3 years ago
What caused wind to blow
Arlecino [84]

Answer:

Different atmospheric pressure. When there is a different atmospheric pressure, air moves from the higher pressure to the lower pressure area which results in what you call <u>WIND</u> but can result in various speeds and pressure.

Hope this helped and if it did, please give my answer a brainliest.

7 0
3 years ago
Read 2 more answers
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