Answer:
a) ΔHvap=35.3395 kJ/mol
b) Tb=98.62 °C
Explanation:
Given the reaction:
C₇H₁₆ (l) ⇔ C₇H₁₆ (g)
Kp=P(C₇H₁₆) since the concentration ratio for a pure liquid is equal to 1.
When
T₁=50°C=323.15K ⇒P₁=0.179
T₂=86°C=359.15K ⇒P₂=0.669
The Clasius-Clapeyron equation is:



ΔHvap=35339.5 J/mol=35.3395 KJ/mol
Normal boiling point ⇒ P=1 atm
Hence, we find the normal boiling point where:
T₁=323.15K
P₁=0.179 atm
P₂=1 atm



T₂=371.77 K= 98.62 °C
A free-radical substitution reaction is likely to be responsible for the observations. The reaction mechanism of a reaction like this can be grouped into three phases:
- Initiation; the "light" on the mixture deliver sufficient amount of energy such that the halogen molecules undergo homologous fission. It typically takes ultraviolet radiation to initiate fissions of the bonds.
- Propagation; free radicals react with molecules to produce new free radicals and molecules.
- Termination; two free radicals combine and form covalent bonds to produce stable molecules. Note that it is possible for two carbon-containing free-radicals to combine, leading to the production of trace amounts of long carbon chains in the product.
Initiation

where the big black dot indicates unpaired electrons attached to the atom.
Propagation






Termination

The element of the group 17 that is most active non metal is fluorine.
The group 17 of the periodic table contains bromine(Br), iodine(I), Chlorine(Cl) and fluorine(F).
Among all the elements of the group 17. Fluorine is the smallest in size.
Because of the small size of fluorine it has the highest electronegativity in group 17.
This high electronegativity makes it a very active non metal. It provides a very high oxidizing power and low dissociation energy to the fluorine atom.
Also because of the very small size the source of attraction between the nucleus and the electrons is very high in floor in atom.
It reacts readily to form oxides and hydroxides.
So, we can conclude here that fluorine is the most active non metal of group 17.
To know more about group 17, visit,
brainly.com/question/26440054
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I think it’s the one that has a Br