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Mumz [18]
3 years ago
9

Calculate the sublimation pressure of the solid at the melting point of 400.00 K assuming that the enthalpy of sublimation is no

t a function of temperature.
Chemistry
1 answer:
nasty-shy [4]3 years ago
6 0

This question is incomplete, the complete question is;

Tonksite is a solid at 300.00K.  At 300.00 K its enthalpy of sublimation is 66.00 kJ/mol. The sublimation pressure at 300.00 K is 5.00 × 10⁻⁴ atm

Calculate the sublimation pressure of the solid at the melting point of 400.00 K assuming that the enthalpy of sublimation is not a function of temperature.

Answer: the sublimation pressure of the solid at the melting point is  0.3727 atm

Explanation:

Given that;

T1 = 300 K

T2 = 400 K

H_sub = 66 kJ/mol = 66000 J/mol

P1 = 5.00 × 10⁻⁴ atm

p2 = ?

now using the expression

log( p2 / 5.00 × 10⁻⁴ ) = (H_sub / R ×  2.303 ) (( T2 - T1) / T1T2)

now we substitute of given values into the expression

log(p2/p1) = (66000 / 8.314 ×  2.303 ) (( 400 - 300) / 300 × 400 )

p2 = 0.3727 atm

therefore the sublimation pressure of the solid at the melting point is  0.3727 atm

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Answer:

The correct answer is D.

Explanation:

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3 years ago
What heat is liberated in the formation of 10.0 grams of sulfur hexafluoride, SF6, from the elements sulfur and fluorine?
tensa zangetsu [6.8K]

Answer:

Q=-76.7kJ

Explanation:

Hello,

In this case, for such formation of sulfur hexafluoride, the standard enthalpy of formation is -1220.47 kJ/mol (data extracted from NIST database). Next, we compute the moles in 10.0 grams of sulfur hexafluoride as shown below:

n_{SF_6}=10.0gSF_6*\frac{1molSF_6}{146.06 gSF_6}=0.0685mol

Next, for the given energy, we compute the total heat that is liberated:

Q=-1220.47\frac{kJ}{mol}*0.0685 mol\\\\Q=-76.7kJ

Finally, we conclude such symbol has sense since negative heat is related with liberated heat.

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3 years ago
The breaking buffer that we use this week contains 10mM Tris, pH 8.0, 150mM NaCl. The elution buffer is breaking buffer that als
olasank [31]

Answer:

A breakdown of the breaking buffer was first listed with its respective component and their corresponding value; then a table was made for the stock concentrations in which the volume that is being added was determined by using the formula M_1*V_1 = M_2*V_2. It was the addition of these volumes altogether that make up the 0.25 L (i.e 250 mL)  with water

Explanation:

Given data includes:

Tris= 10mM

pH = 8.0

NaCl = 150 mM

Imidazole = 300 mM

In order to make 0.25 L solution buffer ; i.e (250 mL); we have the following component.

Stock Concentration             Volume to be             Final Concentration

                                               added            

1 M Tris                                     2.5 mL                         10 mM

5 M NaCl                                  7.5 mL                        150 mM

1 M Imidazole                           75 mL                         300 mM    

M_1*V_1 = M_2*V_2. is the formula that is used to determine the corresponding volume that is added for each stock concentration

The stock concentration of Tris ( 1 M ) is as follows:

M_1*V_1 = M_2*V_2.

1*V_1= 0.01 M *250mL\\V_1 = 2.5mL

The stock concentration of NaCl (5 M ) is as follows:

M_1*V_1 = M_2*V_2.

1*V_1= 0.15 M *250mL\\V_1 = 7.5mL

The stock concentration of Imidazole (1 M ) is as follows:

M_1*V_1 = M_2*V_2.

1*V_1= 0.03 M *250mL\\V_1 = 75mL

Hence, it is the addition of all the volumes altogether that make up 0.25L (i.e 250 mL) with water.

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