The formation of aspirin will proceed faster if acetic anhydride is used in place of acetic acid.
However, acetic anhydride will hydrolyze in the presence of water to form acetic acid, slowing down the reaction.
Answer : The fraction of carbonic acid present in the blood is 5.95%
Explanation :
The mixture consists of carbonic acid ( H₂CO₃) and bicarbonate ion ( HCO₃⁻). This represents a mixture of weak acid and its conjugate which is a buffer.
The pH of a buffer is calculated using Henderson equation which is given below.
![pH = pKa + log \frac{[Base]}{[Acid]}](https://tex.z-dn.net/?f=pH%20%3D%20pKa%20%2B%20log%20%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D)
We have been given,
pH = 7.5
pKa of carbonic acid = 6.3
Let us plug in the values in Henderson equation to find the ratio Base/Acid.
![7.5 = 6.3 + log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=7.5%20%3D%206.3%20%2B%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![1.2 = log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=1.2%20%3D%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![\frac{[Base]}{[Acid]} = 10^{1.2}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2010%5E%7B1.2%7D)
![\frac{[Base]}{[Acid]} = 15.8](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2015.8)
![[Base] = 15.8 \times [Acid]](https://tex.z-dn.net/?f=%5BBase%5D%20%3D%2015.8%20%5Ctimes%20%5BAcid%5D)
The total of mole fraction of acid and base is 1. Therefore we have,
![[Acid] + [Base] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%20%5BBase%5D%20%3D%201)
But Base = 15.8 x [Acid]. Let us plug in this value in above equation.
![[Acid] + 15.8 \times [Acid] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%2015.8%20%5Ctimes%20%5BAcid%5D%20%3D%201)
![16.8 [Acid] = 1](https://tex.z-dn.net/?f=16.8%20%5BAcid%5D%20%3D%201)
![[Acid] = \frac{1}{16.8}](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%20%5Cfrac%7B1%7D%7B16.8%7D)
![[Acid] = 0.0595](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%200.0595)
[Acid] = 0.0595 x 100 = 5.95 %
The fraction of carbonic acid present in the blood is 5.95%
Answer:
The temperature to the nearest 0.5°C is 98.5°C
Answer:In chemistry, a valence electron is an outer shell electron that is associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed; in a single covalent bond, both atoms in the bond contribute one valence electron in order to form a shared pair.
Explanation: hope this helped
Ca(OH)₂: strong base
pOH = a . M
a = valence ( amount of OH⁻)
M = concentration
Ca(OH)₂ ⇒ Ca²⁺ + 2OH⁻ (2 valence)
so:
pOH = 2 x 0.005
pOH = 0.01
pH = 14 - 0.01 = 13.99