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kakasveta [241]
3 years ago
6

The most important commercial process for generating hydrogen gas is the water-gas shift reaction:. CH4(g) + H2O(g) → CO(g) + 3H

2(g). Use tabulated thermodynamic data to find ΔG° for this reaction at the standard temperature of 25°C. i found this to be. =1.423×102 kJ. Now calculate ΔG°1200 for this process when it occurs at 1200 K
Chemistry
2 answers:
Sophie [7]3 years ago
7 0
The Gibb's free energy at a certain temperature is calculated by using the equation,
ΔG = - RT(ln K)

where K is the constant. We calculate this value by using the first conditions,
1.423x10^2 = -(8.314)(25 + 273) x (ln K)

Solving for K,
 K = 0.94418

Use the equation for the second set of conditions,

ΔG = - (8.314)(1200) x (ln 0.94418)

<span>ΔG° at 1200 K is approximately 573.05 kJ</span>
PtichkaEL [24]3 years ago
4 0
The Gibb's free energy at a certain temperature is calculated through the equation,
                                 ΔG = - RT(ln K)
where K is constant. Substituting the values from the first set of the given,
                               1.423x10^2 = -(8.314)(25 + 273) x (ln K)
Solving for the value of K gives us an answer of, K = 0.94418
Use the same equation to get the value of ΔG°1200
                                     ΔG = - (8.314)(1200) x (ln 0.94418)
The value of ΔG°1200 is approximately 573.05 kJ

                 
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Calculate the molarity of 139 grams of sucrose, C12H22O11, in 2.60 liters of solution.
Allisa [31]

Answer:

to calculate the molarity of the said sucrose,

firstly calculate the moles

which is = Molecular weight of C12H22O11 = 342g/mol

then

moles = 139/342

= 0.41 moles

to calculate Molarity now

Molarity= moles of the solute/volume of solution in liter

=0.41/2.60

=0.158M

Explanation:

4 0
3 years ago
When 20.0 g of KI are dissolved in 50.0 mL of distilled water in a calorimeter, the temperature drops from 24.0 °C to 19.0 °C. C
Reil [10]
<h2>Answer:</h2>

<em>8.67kJ/mol</em>

<h2>Explanations</h2>

The formula for calculating the amount of heat absorbed by the water is given as:

\begin{gathered} q=mc\triangle t \\ q=50\times4.18\frac{J}{g^oC}\times(19-24) \\ q=50\times4.18\times(-5) \\ q=-1045Joules \\ q=-1.045kJ \end{gathered}

Determine the moles of KI

\begin{gathered} moles\text{ of KI}=\frac{mass\text{ of KI}}{molar\text{ mass of KI}} \\ moles\text{ of KI}=\frac{20g}{166g\text{/mol}} \\ moles\text{ of KI}=0.1205moles \end{gathered}

Since heat is lost, hence the enthalpy change of the solution will be negative that is:

\begin{gathered} \triangle H=-q \\ \triangle H=-(-1.045kJ) \\ \triangle H=1.045kJ \end{gathered}

Determine the enthalpy of solution in kJ•mol-1

\begin{gathered} \triangle H_{diss}=\frac{1.045kJ}{0.1205mole} \\ \triangle H_{diss}\approx8.67kJmol^{-1} \end{gathered}

Hence the enthalpy of solution in kJ•mol-1 for KI is 8.67kJ/mol

4 0
1 year ago
calculate the volume of air in liters that you might inhale(and exhale)in 8.0 hours. Assume that each breath has a volume of 0.5
maks197457 [2]
Formula:
0.57 liters = 1 breath(17 breaths = 1minute)(60 minutes = 1 hour)(8 hours) = 4651.2 liters

each breath is 0.57 liters
He or she exhales 17(0.57) = 9.69 liters in a minute
in an hour, he or she exhales 9.69(60) liters in a minute = 581.4 liters
Answer = in 8 hours he or she exhales, 581.4(8) = 4651.2 liters in 8 hours


Hope that answers your question!!!!have a great day!!!



6 0
3 years ago
Calculate the mass of excess reagent remaining at the end of the reaction in which 90.0 g of SO2 are mixed with 100.0 g of O2
Radda [10]
We have to first write a balanced equation.
so2 + o2 -> so3

this is not balanced though. we have 3 oxygen on right and 4 on left
2so2 + o2 -> 2so3

now it is same on both sides. we have to figure out which is limiting reagent with the given amounts of reagents. we do this by comparing the ratio between them in terms of moles. we see that so2 has a coefficient of 2 and o2 has none which implies 1 and so3 has 2. this means that for every 2 moles of so2 reacting with 1 mole of o2, we get 2 moles of so3.

lets convert the given values to moles. to do this we know that molecular weight is measured in grams per mole. we are given grams and need to cancel out the grams to get moles. so the molecular weight:
so2 =32.1 + 2 * 16 = 64.1 g/mol
o2 = 2 * 16 = 32 g/mol
so3 = 32.1 + 3 * 16 = 80.1 g/mol

now to convert 90 g of 2so2 under ideal conditions.
90g / 64.1g/mol = 1.404 moles

convert this amount of moles of so2 to moles of o2. we have 2 moles of so2 to 1 of o2
1.404moles so2 / 2 moles so2 * 1 mole o2= 0.702 moles o2

so we see under ideal conditions that 90g of so2 would react with .702g of o2. lets see how many we actually have with 100g of o2
100g / 32g/mol =3.16 mol.

so we have a lot more o2 than needed. we are looking for how much is left in grams. we have to figure out how much was used. to do this convert our ideal moles of o2 into grams.
.702 moles o2 * 32g/mol = 22.5g o2

so what we startrd with (100g) minus what we needed (22.5g) is what we have left
100 - 22.5 = 77.5g o2
6 0
2 years ago
Water has a boiling point of 100.0°C and a Kb of 0.512°C/m. What is the boiling
Neko [114]

Answer:

104.352°C

Explanation:

Data Given:

Boiling point of water = 100.0°C

Kb (boiling point constant = 0.512°C/m

Concentration of the Mg₃(PO₄)₂ = 8.5 m

Solution:

Formula Used to find out boiling point

               ΔTb = m.Kb . . . . . . (1)

where

               ΔTb = boiling point of solution - boiling point of water

So,

we can write equation 1 as under

               ΔTb = Tb (Solution) -Tb (water)

As we have to find out boiling point so rearrange the above equation

              Tb (Solution)  = m.Kb + Tb (water) . . . . . . . (2)

Put values in Equation 2

            Tb (Solution)  = (8.5 m x 0.512°C/m ) + 100.0°C

            Tb (Solution)  = 4.352 + 100.0°C

            Tb (Solution)  = 104.352°C

so the boiling point of Mg₃(PO₄)₂  8.5 m solution =  104.352°C

3 0
3 years ago
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