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Alexandra [31]
3 years ago
5

Tarnish on copper is the compound CuO. A tarnished copper plate is placed in an aluminum pan of boiling water. When enough salt

is added so that the solution conducts electricity, the tarnish disappears. Imagine that the two halves of this redox reaction were separated and connected with a wire and a salt bridge. Part A Calculate the standard cell potential given the following standard reduction potentials: Al3++3e−→Al;E∘=−1.66 V Cu2++2e−→Cu;E∘=0.340 V Express your answer to two decimal places and include the appropriate units.
Chemistry
1 answer:
oksian1 [2.3K]3 years ago
4 0

Answer:

The standard cell potential is 2.00 V

Explanation:

<u>Step 1:</u> Data given

Cu is cathode because of higher EP

Al3++3e−→Al       E∘=−1.66 V     anode

Cu2++2e−→Cu    E∘=0.340 V    cathode

<u>Step 2:</u> Balance both equations

2*(Al → Al3+-3e−)       E∘=1.66 V    

3*(Cu2++2e−→Cu)    E∘=0.340 V

<u>Step 3:</u> The netto equation

2 Al + 3Cu2+ +6e- → 2Al3+ + 3Cu -6e-

2 Al + 3Cu2+  → 2Al3+ + 3Cu

<u>Step 4:</u> Calculate the standard cell potential

E∘cell = E∘cathode - E∘anode

E∘cell = E∘ Cu2+/Cu - E∘ Al3+/Al

E∘cell =0.340 V - (-1.66) = 2.00 V

The standard cell potential is 2.00 V

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