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Feliz [49]
3 years ago
14

The solubility of two slightly soluble salts of M^2+ , MA and MZ_2, are the same, 4 x 10^â4 mol/L.

Chemistry
1 answer:
LekaFEV [45]3 years ago
7 0

Answer:

a) MZ₂

b) They have the same concentration

c) 4x10⁻⁴ mol/L

Explanation:

a) The solubility (S) is the concentration of the salt that will be dissociated and form the ions in the solution, the solubility product constant (Kps) is the multiplication of the concentration of the ions elevated at their coefficients. The concentration of the ions depends on the stoichiometry and will be equivalent to S.

The salts solubilization reactions and their Kps values are:

MA(s) ⇄ M⁺²(aq) + A⁻²(aq) Kps = S*S = S²

MZ₂(aq) ⇄ M⁺²(aq) + 2Z⁻(aq) Kps = S*S² = S³

Thus, the Kps of MZ₂ has a larger value.

b) A saturated solution is a solution that has the maximum amount of salt dissolved, so, the concentration dissolved is solubility. As we can notice from the reactions, the concentration of M⁺² is the same for both salts.

c) The equilibrium will be not modified because the salts have the same solubility. So, let's suppose that the volume of each one is 1 L, so the number of moles of the cation in each one is 4x10⁻⁴ mol. The total number of moles is 8x10⁻⁴ mol, and the concentration is:

8x10⁻⁴ mol/2 L = 4x10⁻⁴ mol/L.

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<h3>What is Homogenization?</h3>

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1 year ago
Consider the following system at equilibrium:
alexgriva [62]

Answer:

A - Increase (R), Decrease (P), Decrease(q), Triple both (Q) and (R)

B - Increase(P), Increase(q), Decrease (R)

C - Triple (P) and reduce (q) to one third

Explanation:

<em>According to Le Chatelier principle, when a system is in equilibrium and one of the constraints that affect the rate of reaction is applied, the equilibrium will shift so as to annul the effects of the constraint.</em>

P and Q are reactants, an increase in either or both without an equally measurable increase in R (a product) will shift the equilibrium to the right. Also, any decrease in R without a corresponding decrease in either or both of P and Q will shift the equilibrium to the right. Hence, Increase(P), Increase(q), and Decrease (R) will shift the equilibrium to the right.

In the same vein, any increase in R without a corresponding increase in P and Q will shift the equilibrium to the left. The same goes for any decrease in either or both of P and Q without a counter-decrease in R will shift the equilibrium to the left. Hence, Increase (R), Decrease (P), Decrease(q), and Triple both (Q) and (R) will shift the equilibrium to the left.

Any increase or decrease in P with a commensurable decrease or increase in Q (or vice versa) with R remaining constant will create no shift in the equilibrium. Hence, Triple (P) and reduce (q) to one third will create no shift in the equilibrium.

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In the reaction below for example;

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If you have moved the position of the equilibrium to the right (and so increased the amount of C and D), why hasn't the equilibrium constant increased?

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