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hoa [83]
3 years ago
12

Methane and hydrogen sulfide form when hydrogen reacts with carbon disulfide. Identify the excess reagent and calculate how much

remains after 36 L of H2 reacts with 12 L of CS2. 4H2(g) + CS2(g) → CH4(g) + 2H2S(g)
Chemistry
1 answer:
Leno4ka [110]3 years ago
8 0

Answer:

There will be produced 9L of CH4 and 18 L of H2S. There will remain 3 L of CS2

Explanation:

Step 1: Data given

volume of H2 = 36.00 L

volume of CS2 = 12 L

Step 2 = the balanced equation

4H2(g) + CS2(g) → CH4(g) + 2H2S(g)

Step 3: Calculate number of moles of H2

1 mol = 22.4 L

36 L = 1.607 mol

Step 4: Calculate moles of CS2

1 mol = 22.4 L

12 L = 0.5357 moles

Step 5: Calculate the limiting reactant

For 4 moles of H2 we need 1 mol of CS2 to produce 1 mol of CH4 and 2 moles of H2S

H2 is the limiting reactant. It will completely be consumed. ( 1.607 moles)

CS2 is in excess. There will react 1.607/4 = 0.40175 moles

There will remain 0.5357 - 0.40175 = 0.13395 moles of CS2

0.13395 moles of CS2 = 3 L

Step 6: Calculate products

For 4 moles of H2 we need 1 mol of CS2 to produce 1 mol of CH4 and 2 moles of H2S

For 1.607 moles of H2 we'll have 0.40175 moles of CH4 (= 9L) and 0.8035 moles of H2S =(18L)

There will be produced 9L of CH4 and 18 L of H2S. There will remain 3 L of CS2

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melomori [17]

Answer:

The correct answer is B. It is spontaneous only at low temperatures.

Explanation:

In thermodynamics, the Gibbs free energy is a thermodynamic potential that can be used to calculate the maximum of reversible work that may be performed by a thermodynamic system at a constant temperature and pressure.

The spontaneity of a reaction is given by the equation:

ΔG = ΔH - TΔS

where:

ΔH: enthalpy variation

T: absolute temperature

ΔS: entropy variation

As the reaction is exothermic, ΔH<0

As the reaction order increases (the reagents are solid and gas and their product is solid), ΔS<0

Therefore, the reaction will be spontaneous when ΔG is negative.

ΔG = ΔH - TΔS

That is, the entropy term must be smaller than the enthalpy term.

Hence, the reaction will be spontaneous only at low temperatures.

4 0
3 years ago
Use Hess's Law to calculate the enthalpy change for the reaction
Marysya12 [62]

Answer:

ΔH = 125.94kJ

Explanation:

It is possible to make algebraic sum of reactions to obtain ΔH of reactions (Hess's law). In the problem:

1. 2W(s) + 3O2(g) → 2WO3(s) ΔH = -1685.4 kJ

2. 2H2(g) + O2(g) → 2H2O(g) ΔH = -477.84 kJ

-1/2 (1):

WO3(s) → W(s) + 3/2O2(g) ΔH = 842.7kJ

3/2 (2):

3H2(g) + 3/2O2(g) → 3H2O(g) ΔH = -716.76kJ

The sum of  last both reactions:

WO3(s) + 3H2(g) → W(s) + 3H2O(g)

ΔH = 842.7kJ -716.76kJ

<h3>ΔH = 125.94kJ </h3>
3 0
3 years ago
In bullet points: explain the difference between thermal energy, heat and temperature.
sergeinik [125]
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  • Heat-energy is the result of the movement of tiny particles called atoms, molecules or ions in solids, liquids and gases. Heat energy can be transferred from one object to another. The transfer or flow due to the difference in temperature between the two objects.

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3 0
3 years ago
How many moles of PC15 can be produced from 51.0 g of Cl2 (and excess P4)?
slava [35]

Answer:

0.287 mole of PCl5.

Explanation:

We'll begin by calculating the number of mole in 51g of Cl2. This is illustrated below:

Molar mass of Cl2 = 2 x 35.5 = 71g/mol

Mass of Cl2 = 51g

Number of mole of Cl2 =..?

Mole = Mass /Molar Mass

Number of mole of Cl2 = 51/71 = 0.718 mole

Next, we shall write the balanced equation for the reaction. This is given below:

P4 + 10Cl2 → 4PCl5

Finally, we determine the number of mole of PCl5 produced from the reaction as follow:

From the balanced equation above,

10 moles of Cl2 reacted to produce 4 moles of PCl5.

Therefore, 0.718 mole of Cl2 will react to produce = (0.718 x 4)/10 = 0.287 mole of PCl5.

Therefore, 0.287 mole of PCl5 is produced from the reaction.

8 0
3 years ago
After examining the graphs, the scientist could
Ivanshal [37]
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They need more oxygen due to higher temperatures
5 0
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