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hoa [83]
3 years ago
12

Methane and hydrogen sulfide form when hydrogen reacts with carbon disulfide. Identify the excess reagent and calculate how much

remains after 36 L of H2 reacts with 12 L of CS2. 4H2(g) + CS2(g) → CH4(g) + 2H2S(g)
Chemistry
1 answer:
Leno4ka [110]3 years ago
8 0

Answer:

There will be produced 9L of CH4 and 18 L of H2S. There will remain 3 L of CS2

Explanation:

Step 1: Data given

volume of H2 = 36.00 L

volume of CS2 = 12 L

Step 2 = the balanced equation

4H2(g) + CS2(g) → CH4(g) + 2H2S(g)

Step 3: Calculate number of moles of H2

1 mol = 22.4 L

36 L = 1.607 mol

Step 4: Calculate moles of CS2

1 mol = 22.4 L

12 L = 0.5357 moles

Step 5: Calculate the limiting reactant

For 4 moles of H2 we need 1 mol of CS2 to produce 1 mol of CH4 and 2 moles of H2S

H2 is the limiting reactant. It will completely be consumed. ( 1.607 moles)

CS2 is in excess. There will react 1.607/4 = 0.40175 moles

There will remain 0.5357 - 0.40175 = 0.13395 moles of CS2

0.13395 moles of CS2 = 3 L

Step 6: Calculate products

For 4 moles of H2 we need 1 mol of CS2 to produce 1 mol of CH4 and 2 moles of H2S

For 1.607 moles of H2 we'll have 0.40175 moles of CH4 (= 9L) and 0.8035 moles of H2S =(18L)

There will be produced 9L of CH4 and 18 L of H2S. There will remain 3 L of CS2

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A certain reaction has an activation energy of 67.0 kJ/mol and a frequency factor of A1 = 4.20×1012. What is the rate constant,
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Answer:

  • K = 7.00

Explanation:

<u>1) Arrhenius equation</u>

Arrhenius equation shows the relation between activation energy, temperature, and the equilibrium constant.

This is the equation:

       K=Ae^{-Ea/RT}

Where:

  • K is the equilibrium constant,
  • A is the frequency factor,
  • Ea is the activation energy (in J/mol),
  • T is the temperature in kelvins (K), and
  • R is the universal constant.

<u></u>

<u>2) Substitute, using the right units, and compute:</u>

  • A = 4.20 × 10¹² (dimensionless)
  • Ea = 67.0 kJ/mol = 67,000 J/mol
  • T = 24.0°C = 24.0 + 273.15 K = 297.15 K
  • R = 8.314 J/K mol

K=Ae^{-Ea/RT}=(4.20)(10)^{12}e^{-67,000J/mol/(8.314J/molK.297.15K)}

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5 0
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Which of the following statements is true?
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A sample of an unknown gas effuses in 14.4 min. An equal volume of H2 in the same apparatus under the same conditions effuses in
Elena-2011 [213]

Answer:- molar mass of the unknown gas is 71.5 gram per mol.

Solution:- From Graham's law of effusion rates, the rate of effusion of a gas is inversely proportional to the square root of it's molar mass.

When we compare the effusion rates of two gases then the formula for Graham's law is:

\frac{rate_1}{rate_2}=\sqrt{\frac{M_2}{M_1}}

In this formula, V stands for volume and M stands for molar mass

Rate is volume effused per unit time. Since, the volumes are same, the formula could be written as:

\frac{t_2}{t_1}=\sqrt{\frac{M_2}{M_1}}

let's say in formula, subscript 1 is for hydrogen gas and 2 is for the unknown gas.

Molar mass of hydrogen is 2.02 grams per mol and the time taken to effuse it is 2.42 min. The time taken to effuse the unknown gas is 14.4 min and we are asked to calculate it's molar mass. let's plug in the values in the formula:

\frac{14.4}{2.42}=\sqrt{\frac{M_2}{2.02}}

5.95=\sqrt{\frac{M_2}{2.02}}

doing squares to both sides:

35.4=\frac{M_2}{2.02}

M_2=35.4*2.02

M_2=71.5

So, the molar mass of the unknown gas is 71.5 grams per mol.



4 0
3 years ago
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