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jek_recluse [69]
3 years ago
11

Select the compounds that cannot undergo friedel crafts alkylation. check all that apply. check all that apply. aniline phenol k

etones halobenzenes benzene nitrobenzene anisole benzensulfonic acid toluene
Chemistry
1 answer:
mr Goodwill [35]3 years ago
5 0

Freidal craft reaction is the attack of a carbon or carbon chain on aromatic ring with the help of anhydrous AlCl3 to produce alkylated benzene ring.

Only ketone not be able to undergo friedal craft reaction as, it is not aromatic compound whereas all the given reactants are aromatic and gives friedal craft reaction.

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Comparing the 2-bromobutane + methoxide and 2-bromobutane + t-butoxide reactions, choose the statements that BEST describe the d
Elina [12.6K]

Answer:

an increase in 1-butene was observed when t-butoxide was used

Explanation:

When a base reacts with an alkyl halide, an elimination product is formed. This reaction is an E2 reaction.

Here we are to compare the reaction of two different bases with one substrate; 2-bromobutane. Both reactions occur by the E2 mechanism but follow different transition states due to the size of the base.

The Saytzeff product, 2-butene, is obtained when the methoxide is used while the non Saytzeff product, 1-butene, is obtained when t-butoxide is used.

The Saytzeff rule is reliable in predicting the major products of simple elimination reactions of alkyl halides given the fact that a small/strong bases is used for the elimination reaction. Therefore hydroxide, methoxide and ethoxide bases give similar results for the same alkyl halide substrate. Bulky bases such as tert-butoxide tend to yield a higher percentage of the non Saytzeff product and this is usually attributed to steric hindrance.

8 0
3 years ago
The expression of the theoretical yield (TY) in function of limiting reagent (LR) of a reaction is as follows: TY = ideal mole r
spin [16.1K]

<u>Answer:</u> The theoretical yield of acetanilide is 6.5 grams.

<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}      .....(1)

  • <u>For aniline:</u>

Given mass of aniline = 4.50\times 10^0=4.50g      (We know that:  10^0=1 )

Molar mass of aniline = 93.13 g/mol

Putting values in equation 1, we get:

\text{Moles of aniline}=\frac{4.50g}{93.13g/mol}=0.048mol

  • <u>For acetic anhydride:</u>

To calculate the mass of acetic anhydride, we use the equation:

\text{Density of substance}=\frac{\text{Mass of substance}}{\text{Volume of substance}}

Volume of acetic anhydride = (1.25\times \text{Mass of aniline})=1.25\times 4.50=5.625mL

Density of acetic anhydride = 1.08 g/mL

Putting values in above equation:

1.08g/mL=\frac{\text{Mass of acetic anhydride}}{5.625mL}\\\\\text{Mass of acetic anhydride}=(1.08g/mL\times 5.625mL)=6.08g

Given mass of acetic anhydride = 6.08 g

Molar mass of acetic anhydride = 102.1 g/mol

Putting values in equation 1, we get:

\text{Moles of acetic anhydride}=\frac{6.08g}{102.1g/mol}=0.06mol

The chemical equation for the reaction of aniline and acetic anhydride follows:

C_6H_5NH_2+CH_3COOCOCH_3\rightarrow C_6H_5NHCOCH_3+CH_3COOH

By Stoichiometry of the reaction:

1 mole of aniline reacts with 1 mole of acetic anhydride

So, 0.048 moles of aniline will react with = \frac{1}{1}\times 0.048=0.048mol of acetic anhydride

As, given amount of acetic anhydride is more than the required amount. So, it is considered as an excess reagent.

Thus, aniline is considered as a limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

1 mole of aniline produces 1 mole of acetanilide

So, 0.048 moles of aniline will produce = \frac{1}{1}\times 0.048=0.048mol of acetanilide

Now, calculating the theoretical yield of acetanilide by using equation 1:

Moles of acetanilide = 0.048 moles

Molar mass of acetanilide = 135.17 g/mol

Putting values in equation 1, we get:

0.048mol=\frac{\text{Mass of acetanilide}}{135.17g/mol}\\\\\text{Mass of acetanilide}=(0.048mol\times 135.17g/mol)=6.5g

Hence, the theoretical yield of acetanilide is 6.5 grams.

3 0
3 years ago
Which statement best describes insoluble substances?
Maksim231197 [3]

Answer:

Water does not remain when an insoluble substance is added

7 0
3 years ago
Read 2 more answers
The removal of one or more electrons from a neutral atom results in and
Studentka2010 [4]

Answer:

The removal of one or more electrons from a neutral atom results in a cation.

Explanation:

When you remove electrons from a neutral atom, the atom becomes more positive. Electrons have a negative charge and the protons inside of the nucleus have a positive charge. When electrons are removed, the positive charges from the protons outweigh the negative charges. This results in a positively charged atom, called a cation.

6 0
1 year ago
How much time would it take for 336 mg of copper to be plated at a current of 5.6 A ? Express your answer using two significant
schepotkina [342]

Answer:

1.8 × 10² s

Explanation:

Let's consider the reduction that occurs upon the electroplating of copper.

Cu²⁺(aq) + 2 e⁻ ⇒ Cu(s)

We will establish the following relationships:

  • 1 g = 1,000 mg
  • The molar mass of Cu is 63.55 g/mol
  • When 1 mole of Cu is deposited, 2 moles of electrons circulate.
  • The charge of 1 mole of electrons is 96,486 C (Faraday's constant).
  • 1 A = 1 C/s

The time  that it would take for 336 mg of copper to be plated at a current of 5.6 A is:

336mgCu \times \frac{1gCu}{1,000mgCu} \times \frac{1molCu}{63.55gCu} \times \frac{2mole^{-} }{1molCu} \times \frac{94,486C}{1mole^{-}} \times \frac{1s}{5.6C} = 1.8 \times 10^{2} s

3 0
3 years ago
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