Answer:
The rate law for second order unimolecular irreversible reaction is
![\frac{1}{[A]} = k.t + \frac{1}{[A]_{0} }](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%20%3D%20k.t%20%2B%20%5Cfrac%7B1%7D%7B%5BA%5D_%7B0%7D%20%7D)
Explanation:
A second order unimolecular irreversible reaction is
2A → B
Thus the rate of the reaction is
![v = -\frac{1}{2}.\frac{d[A]}{dt} = k.[A]^{2}](https://tex.z-dn.net/?f=v%20%3D%20-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D%20%3D%20k.%5BA%5D%5E%7B2%7D)
rearranging the ecuation
![-\frac{1}{2}.\frac{k}{dt} = \frac{[A]^{2}}{d[A]}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bk%7D%7Bdt%7D%20%3D%20%5Cfrac%7B%5BA%5D%5E%7B2%7D%7D%7Bd%5BA%5D%7D)
Integrating between times 0 to <em>t </em>and between the concentrations of ![[A]_{0}](https://tex.z-dn.net/?f=%5BA%5D_%7B0%7D)
to <em>[A].</em>
![\int\limits^0_t -\frac{1}{2}.\frac{k}{dt} =\int\limits^A_{0} _A\frac{[A]^{2}}{d[A]}](https://tex.z-dn.net/?f=%5Cint%5Climits%5E0_t%20-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bk%7D%7Bdt%7D%20%3D%5Cint%5Climits%5EA_%7B0%7D%20_A%5Cfrac%7B%5BA%5D%5E%7B2%7D%7D%7Bd%5BA%5D%7D)
Solving the integral
Answer:
Atoms with 5 or more valence electrons gain electrons forming a negative ion, or anion. why are outermost electrons only ones included in orbital filling diagram? they are the only ones involved in chemical reactions and bonding. ... 2s orbital is farther from the nucleus meaning it has more energy.
Explanation:
These waxes are highly hydrophobic (repellant) of water, so the correct answer would be D) repel.
The wax coating put on the car creates a water repellant sheila that causes the water to bead up on the surface of the wax, rather than directly impacting the paint and surface of the body of the car. This prolongs the life and quality of the appearance of the car.
Answer:
3 years
Explanation:
Given data:
Initial amount of sample = 160 Kg
Amount left after 12 years = 10 Kg
Half life = ?
Solution:
at time zero = 160 Kg
1st half life = 160/2 = 80 kg
2nd half life = 80/2 = 40 kg
3rd half life = 40 / 2 = 20 kg
4th half life = 20 / 2 = 10 kg
Half life:
HL = elapsed time / half life
12 years / 4 = 3 years
