First, recognize that this is an elimination reaction in which hydroxide must leave and a double bond must form in its place. It is likely an E2 reaction. Here is an efficient mechanism:
1) Pre-reaction: Protonate the -OH to make it a good leaving group, water. H2SO4 or any strong H+ donor works. The water is positively charged but still connected to the compound.
2) E2: Use a sterically hindered base, such as tert-butoxide (tButO-) to abstract the hydrogen from the secondary carbon. [You want a sterically hindered base because a strong, non-sterically hindered base could also abstract a hydrogen from one of the two methyl groups on the tertiary carbon, and that leads to unwanted products, which is not efficient]. As the proton of hydrogen is abstracted, water leaves at the same time, creating an intermediate tertiary carbocation, and the 2 electrons in the C-H bond immediately are used to make a double bond towards the partial positive charge.
In the products we see the major product and water, as expected. Even though you have an intermediate, remember that an E2 mechanism technically happens in one step after -OH protonation.
Answer:
V₂ = 648.53 mL
Explanation:
Given data:
Initial volume of gas = 490. mL
Initial temperature = -35°C (-35 + 273 = 238 k)
Final temperature = 42°C = (42+273 = 315 k)
Final volume = ?
Solution:
The given problem will be solve through the Charles Law.
According to this law, The volume of given amount of a gas is directly proportional to its temperature at constant number of moles and pressure.
Mathematical expression:
V₁/T₁ = V₂/T₂
V₁ = Initial volume
T₁ = Initial temperature
V₂ = Final volume
T₂ = Final temperature
Now we will put the values in formula.
V₁/T₁ = V₂/T₂
V₂ = V₁T₂/T₁
V₂ = 490 mL × 315 K / 238 k
V₂ = 154350 mL.K / 238 K
V₂ = 648.53 mL
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Answer:
The answer is explained below
Explanation:
If you add dilute HCl (Hydrochloric Acid) to the solution, and you see fizzing, then it is the carbonate. I would recommend doing this under a fume hood, as HCl has a wicked smell, and can make a few people sick to their stomach (however, you probably won't be using 12M concentrated HCl)
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