Answer:
526g is the mass of this sample
Explanation:
To solve this question we must, as first, find the <em>molar mass </em>of Al₂(Cr₂O₇)₃ using the periodic table. The molar mass is defined as the mass of this compound per mole. With this value we can find the mass in 0.750 moles as follows:
<em>Molar mass Al₂(Cr₂O₇)₃</em>
2Al = 2*26.98g/mol = 53.96g/mol
6 Cr = 6*51.9961g/mol = 311.9766g/mol
21 O = 21*15.999g/mol = 335.979g/mol
53.96g/mol + 311.9766g/mol + 335.979g/mol
= 701.9156g/mol
The mass of 0.750 moles is:
0.750 moles * (701.9156g / mol) =
<h3>526g is the mass of this sample</h3>
<span>C7H8
First, lookup the atomic weight of all involved elements
Atomic weight of carbon = 12.0107
Atomic weight of hydrogen = 1.00794
Atomic weight of oxygen = 15.999
Then calculate the molar masses of CO2 and H2O
Molar mass CO2 = 12.0107 + 2 * 15.999 = 44.0087 g/mol
Molar mass H2O = 2 * 1.00794 + 15.999 = 18.01488 g/mol
Now calculate the number of moles of each product obtained
Note: Not interested in the absolute number of moles, just the relative ratios. So not going to get pedantic about the masses involved being mg and converting them to grams. As long as I'm using the same magnitude units in the same places for the calculations, I'm OK.
moles CO2 = 3.52 / 44.0087 = 0.079984
moles H2O = 0.822 / 18.01488 = 0.045629
Since each CO2 molecule has 1 carbon atom, I can use the same number for the relative moles of carbon. However, since each H2O molecule has 2 hydrogen atoms, I need to double that number to get the relative number of moles for hydrogen.
moles C = 0.079984
moles H = 0.045629 * 2 = 0.091258
So we have a ratio of 0.079984 : 0.091258 for carbon and hydrogen. We need to convert that to a ratio of small integers. First divide both numbers by 0.079984 (selected since it's the smallest), getting
1: 1.140953
The 1 for carbon looks good. But the 1.140953 for hydrogen isn't close to an integer. So let's multiply the ratio by 1, 2, 3, 4, ..., etc and see what each new ratio looks like (Effectively seeing what 1, 2, 3, 4, etc carbons look like)
1 ( 1 : 1.140953) = 1 : 1.140953
2 ( 1 : 1.140953) = 2 : 2.281906
3 ( 1 : 1.140953) = 3 : 3.422859
4 ( 1 : 1.140953) = 4 : 4.563812
5 ( 1 : 1.140953) = 5 : 5.704765
6 ( 1 : 1.140953) = 6 : 6.845718
7 ( 1 : 1.140953) = 7 : 7.986671
8 ( 1 : 1.140953) = 8 : 9.127624
That 7.986671 in row 7 looks extremely close to 8. I doubt I'd get much closer unless I go to extremely high integers. So it looks like the empirical formula for toluene is C7H8</span>
Answer:
a) a = 3485 M⁻¹cm⁻¹
b) C = 0,000127 M
Explanation:
Lambert-Beer law says that there is a linear relationship between absorbance and concentration of a chemical substance. The formula is:
A = a×b×C
Where A is absorbance, a is molar absorptivity, b is path length and C is concentration.
a) In the problem Concentration is 0.0000792 M, b is 1,000cm and Absorbance is absorbance of sample-absorbance of blank: 0,341-0,065 = 0,276
Replacing:
0,276 = a×1,000cm×0,0000792M
<em>a = 3485 M⁻¹cm⁻¹</em>
b) As the experiment consist in the same compound in the same solvent, the molar absorptivity will be the same, a = 3485 M⁻¹cm⁻¹, path length will be 1,000cm and absorbance: 0,508-0,065 = 0,443
Replacing:
0,443 = 3485 M⁻¹cm⁻¹×1,000cm×C
<em>C = 0,000127 M </em>
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I hope it helps!
