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Sav [38]
3 years ago
12

A thermos contains 150 cm3 of coffee at 85 ????C. To cool the coffee, you drop two 11-g ice cubes into the thermos. The ice cube

s are initially at 0 ????C and melt completely. What is the final temperature of the coffee? Treat the coffee as if it were water.
Chemistry
1 answer:
NNADVOKAT [17]3 years ago
3 0

Answer:

73.73°C is the final temperature of the coffee.

Explanation:

Heat lost by the coffee = Q

Mass of the coffee = m

Volume of coffee = V = 150 cm^3=150 mL (1cm^3=1 mL)

Density of water = Density of coffee solution = d = 1 g/mL (given)

Mass =density\times volume

m=1 g/mL\times 150 mL=150 g

Heat capacity of the coffee is equal to that of water= c = 4.18 J/g°C

Initial temperature of the coffee = T_1=85^oC

Final temperature of the coffee = T

Q=mc\times (T-T_1)

Heat required to melt 11 grams of melt ice = Q'

Latent heat of ice = \Delta H_{lat}=334 J/g

Q'=334J/g\times 11g=3674 J

Heat absorbed by the ice after melting = q

Mass of ice melted into water = m' = 11 g

Heat capacity of water = c = 4.18 J/g°C

Initial temperature of water =T_2 = 0°C

Final temperature of water = T

q=m'\times c\times (T_2-T)

According law of conservation of energy , energy lost by coffee will equal to heat required to melt ice and further to raise the temperature of water.

-Q=Q'+q

-(mc\times (T-T_1))=m'\times c\times (T-T_2)+3674 J

150 g\times 4.18 J/g^oC\times (85^oC-T)=11 g\times 4.18 J/g^oC\times (T-0^oC)+3674 J

On solving we get:

T = 73.73°C

73.73°C is the final temperature of the coffee.

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</span>

<span>Explanation:


1) Convert 1.38 g of Fe₂S₃ into number of moles, n


</span>i) Formula: n = mass in grass / molar mass
<span>
ii) molar mass of </span><span>Fe₂S₃ =2 x 55.8 g/mol + 3 x 32.1 g/mol = 207.9 g/mol
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iii) n = 1.38 g / 207.9 g/mol = 0.00664 moles of <span>Fe₂S₃
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<span>2) Use the percent yield to calculate the theoretical amount:
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3) Chemical equation:
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<span> 3 Na₂S(aq) + 2 FeCl₃(aq) → Fe₂S₃(s) + 6 NaCl(aq)


4) Stoichiometrical mole ratios:
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<span>3 mol Na₂S : 2 mol FeCl₃ : 1 mol Fe₂S₃ : 6 mol NaCl


5) Proportionality:


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<span>
=> x = 0.020 mol FeCl₃


6) convert 0.020 mol to volume
</span>

<span>i) Molarity formula: M = n / V
</span>

<span>ii) V = n / M = 0.020 mol / 0.2 M = 0.1 liter = 100 ml
</span>

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