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harkovskaia [24]
3 years ago
9

You are using a beaker to measure volume. the beakers graduation begin at 20ml and in indicate every 10ml up to 80 ml. the botto

m of the meniscus is about three fourths of the way between 40ml mark and the 50 ml mark. you should report this number as:
a)40ml
b)47ml
c)50ml
d)47.0 ml
Chemistry
1 answer:
dolphi86 [110]3 years ago
6 0

Answer:

b) 47ml

Explanation:

The beaker would look like this:

60 mL

50 mL

-------  The bottom of the meniscus is here

40 mL

30 mL

So <u>we have between 40 and 50 mL</u>. There are 10 mL of "distance" between those two values, and three fourths of that difference is (10 * 3/4) 7.5 mL.

So <em>the volume is 47.5 mL</em>, but because the measurement instrument (the beaker) does not handle decimals, the value we should report is 47 mL.

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A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M HCl to reach the equivalenc
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Answer:

a. 0.180M of C₆H₅NH₂

b. 0.0887M C₆H₅NH₃⁺

c. pH = 2.83

Explanation:

a. Based in the chemical equation:

C₆H₅NH₂(aq) + HCl(aq) → C₆H₅NH₃⁺(aq) + Cl⁻(aq)

<em>1 mole of aniline reacts per mole of HCl</em>

Moles required to reach equivalence point are:

Moles HCl = 0.02567L ₓ (0.175mol / L) = 4.492x10⁻³ moles HCl = moles C₆H₅NH₂

As the original solution had a volume of 25.0mL = 0.0250L:

4.492x10⁻³ moles C₆H₅NH₂ / 0.0250L = 0.180M of C₆H₅NH₂

b. At equivalence point, moles of C₆H₅NH₃⁺ are equal to initial moles of C₆H₅NH₂, that is 4.492x10⁻³ moles

But now, volume is 25.0mL + 25.67mL = 50.67mL = 0.05067L. Thus, molar concentration of C₆H₅NH₃⁺ is:

[C₆H₅NH₃⁺] = 4.492x10⁻³ moles / 0.05067L = 0.0887M C₆H₅NH₃⁺

c. At equivalence point you have just 0.0887M C₆H₅NH₃⁺ in solution. C₆H₅NH₃⁺ has as equilibrium in water:

C₆H₅NH₃⁺(aq) + H₂O(l) → C₆H₅NH₂ + H₃O⁺

Where Ka = Kw / Kb = 1x10⁻¹⁴ / 4.0x10⁻¹⁰ =

<em>2.5x10⁻⁵ = [C₆H₅NH₂] [H₃O⁺] / [C₆H₅NH₃⁺]</em>

When the system reaches equilibrium, molar concentrations are:

[C₆H₅NH₃⁺] = 0.0887M - X

[C₆H₅NH₂] = X

[H₃O⁺] = X

Replacing in Ka formula:

2.5x10⁻⁵ = [X] [X] / [0.0887M - X]

2.2175x10⁻⁶ - 2.5x10⁻⁵X = X²

0 = X² + 2.5x10⁻⁵X - 2.2175x10⁻⁶

Solving for X:

X = -0.0015 → False solution. There is no negative concentrations.

X = 0.001477 → Right solution.

As [H₃O⁺] = X, [H₃O⁺] = 0.001477

Knowing pH = -log [H₃O⁺]

pH = -log 0.001477

<h3>pH = 2.83</h3>

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