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Lena [83]
3 years ago
15

A gas evolved during the fermentation of alcohol had a volume of 19.4 L at 17 °C and 746 mmHg. How many moles of gas were collec

ted?
Chemistry
1 answer:
AlexFokin [52]3 years ago
4 0

Answer:- 0.800 moles of the gas were collected.

Solution:- Volume, temperature and pressure is given for the gas and asks to calculate the moles of the gas.

It is an ideal gas law based problem. Ideal gas law equation is used to solve this. The equation is:

PV=nRT

Since it asks to calculate the moles that is n, so let's rearrange this for n:

n=\frac{PV}{RT}

V = 19.4 L

T = 17 + 273 = 290 K

P = 746 mmHg

we need to convert the pressure from mmHg to atm and for this we divide by 760 since, 1 atm = 760 mmHg

P=746mmHg(\frac{1atm}{760mmHg})

P = 0.982 atm

R = 0.0821\frac{atm.L}{mol.K}

Let's plug in the values in the equation to get the moles.

n=\frac{0.982atm*19.4L}{0.0821\frac{atm.L}{mol.K}*290K}

n = 0.800 moles

So, 0.800 moles of the gas were collected.

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d) When frequency of the light exceeds v₀, there is an increase of electron kinetic energy from zero steadily upwards with a constant slope. This is because, once light frequency exceeds, v₀, its energy too exceeds the work function of the metal and the electrons instantaneously gain the energy of incident light and convert this energy to kinetic energy by breaking free and going into motion. The energy keeps increasing as the energy and frequency of incident light increases and electrons gain more speed.

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Explanation:

The plot for this question which is attached to this solution has Electron kinetic energy on the y-axis and frequency of incident light on the x-axis.

a) Wavelength, λ = 680 nm = 680 × 10⁻⁹ m

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v₀ = (3 × 10⁸)/(680 × 10⁻⁹) = 4.41 × 10¹⁴ s⁻¹

b) Work function, W₀ = energy of the light photons with the wavelength of v₀ = E = hv₀

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= 1.76 × 10⁵ J/mol of ejected electrons = 176 KJ/mol of ejected electrons

c) Light of frequency less than v₀ does not possess enough energy to cause electrons to break free from the metal surface. The energy of light with frequency less than v₀ is less than the work function of the metal (which is the minimum amount of energy of light required to excite electrons on metal surface enough to break free).

As evident from the graph, electron kinetic energy remains at zero as long as the frequency of incident light is less than v₀.

d) When frequency of the light exceeds v₀, there is an increase of electron kinetic energy from zero steadily upwards with a constant slope. This is because, once light frequency exceeds, v₀, its energy too exceeds the work function of the metal and the electrons instantaneously gain the energy of incident light and convert this energy to kinetic energy by breaking free and going into motion. The energy keeps increasing as the energy and frequency of incident light increases and electrons gain more speed.

e) The slope of the line segment gives the Planck's constant. From the mathematical relationship, E = hv₀,

And the slope of the line segment is Energy of ejected electrons/frequency of incident light, E/v₀, which adequately matches the Planck's constant, h = 6.63 × 10⁻³⁴ J.s

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