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RSB [31]
3 years ago
5

The condition that a reaction takes place without outside help Choose... Solution in which no more solute can be dissolved in th

e solvent Choose... Difference of the enthalpy (of a system) minus the product of the entropy and absolute temperature Choose... The extent of randomness in a system Choose... Sum of the internal energy plus the product of the pressure and volume for a reaction
Chemistry
1 answer:
11Alexandr11 [23.1K]3 years ago
4 0

Answer:

Difference of the enthalpy (of a system) minus the product of the entropy and absolute temperature

Explanation:

The basis of spontaneity in a chemical reaction is that ∆G must be negative. ¡∆G is known as the change in free energy of a system. If ∆G is negative, then the reaction will occur without any external help (the reaction is spontaneous at room temperature).

∆G is given by;

∆G= ∆H -T∆S

Where;

∆H= change in enthalpy of the system

T= absolute temperature of the system

∆S= change in entropy

Hence; when ∆H -T∆S gives a negative result, the reaction proceeds without any external help.

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Calculate the concentration of acetate ion in a buffer solution made from 2.00 mL of 0.50 M acetic acid and 8.00 mL of 0.50 sodi
Lelu [443]

Answer:

1 M

Explanation:

Equation of reaction is;

CH3COOH + CH3COONa -------------------> 2CH3COO^- + NaH

1 moles of each of the reactants react to give 2 moles of the acetate ion.

From the question, we have that 2.00 mL that is (2÷1000)L of 0.50 M acetic acid reacted with 8.00 mL that is (8/1000)L of 0.50 sodium acetate.

Then from equation, n = CV -------------------------------------------(1).

Where n= number of moles, V= volume, C= concentration.

Number of moles,n of acetic acid = 0.50M× 2/1000L.

n(acetic acid)= 0.001 moles.

Number of moles,n of sodium acetate= 0.50M ×(8/1000)L.

n(sodium acetate)= 0.004 moles.

0.001 moles of acetic acid react with 0.004 moles of Sodium acetate

Therefore, acetic acid is the limiting reagent.

One mole of acetic acid produces 2 moles of acetate ion.

0.001 mole of acetic acid produces= 0.002 moles of acetate ion.

Using the equation (1) that is, n= CV.

0.002= C× 2/1000

C= 0.002/0.002

C= 1 M

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