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3 years ago

In the molecule of SO2 there are two pie bonds these are formed Due to

1 answer:

4 0

These are formed when, after formation of the first atom, the pi-orbitals of Sulfur and Oxygen align and share another pair of electrons. This occurs between sulfur and both of the oxygen atoms, with each oxygen atom forming one pi-bond.

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A gas mixture contains HBr, NO2, and C2H6 at STP. If a tiny hole is made in the container, which gas will effuse fastest? NO2 C2

Anarel [89]

Answer:

C2H6

Explanation:

Let us first consider the molar Masses of each gas

HBr - 80.91 g/mol

NO2 - 46.0055 g/mol

C2H6 - 30.07 g/mol

We must remember that the greater the molar mass of a gas the lesser its velocity and average kinetic energy.

Looking at the gases listed, C2H6 have the highest average kinetic energy at this temperature since it has the lowest molecular mass. This reasoning is directly derived from Graham's law of diffusion in gases.

Hence C2H6 will effuse fastest when a hole is made in the container. It also possess the greatest average kinetic energy because it has the lowest molecular mass.

5 0

2 years ago

A 25.0 mL solution of 0.100 M CH3COOH is titrated with a 0.200 M KOH solution. Calculate the pH after the following additions of

zaharov [31]

Answer:

a) pH = 2.88

b) pH = 4.598

c) pH = 5.503

d) pH = 8.788

e) pH = 12.097

Explanation:

CH3COOH ↔ CH3COO- + H3O+

∴ Ka = 1.75 E-5 = [H3O+]*[CH3COO-] / [CH3COOH]

a) 0.0 mL KOH:

mass balance:

⇒ C CH3COOH = [CH3COOH] + [CH3COO-] = 0.100 M

charge balance:

⇒ [H3O+] = [CH3COO-]

⇒ 1.75 E-5 = [H3O+]²/(0.100 - [H3O+])

⇒ [H3O+]² + 1.75 E-5[H3O+] - 1.75 E-6 = 0

⇒ [H3O+] = 1.314 E.3 M

∴ pH = - Log [H3O+]

⇒ pH = 2.88

b) 5.0 mL KOH:

CH3COOH + KOH ↔ CH3COONa + H2O

∴ C CH3COOH = ((0.025)(0.100) - (5 E-3)(0.200))/(0.025+5 E-3)

⇒ C CH3COOH = 0.05 M

∴ C KOH = ((5 E-3)(0,200))/(0.025+5 E-3) = 0.033 M

mass balance:

⇒ C CH3COOH + C KOH = [CH3COOH] + [CH3COO-] = 0.05 + 0.033 = 0.083 M

charge balance:

⇒ [H3O+] + [K+] = [CH3COO-]

⇒ [CH3COO-] = [H3O+] + 0.033

⇒ 1.75 E-5 = ([H3O+]*([H3O+] + 0.033))/(0.083 - ([H3O+] + 0.033))

⇒ 1.75 E-3 = ([H3O+]² + 0.033[H3O+])/(0.05 - [H3O+])

⇒ 8.75 E-7 - 1.75 E-5[H3O+] = [H3O+]² + 0.033[H3O+]

⇒ [H3O+]² +0.03302[H3O+] - 8.75 E-7 = 0

⇒ [H3O+] = 2.523 E-5 M

⇒ pH = 4.598

equivalent point:

(C*V)acid = (C*V)base

⇒ (0.100 M)*(0.025 L) = (0.200 M)( Vbase)

⇒ Vbase = 0.0125L = 12.5 mL

c) 10.0 mL KOH:

∴ C CH3COOH = 0.0143 M

∴ C KOH = 0.057 M

as in the previous point, starting from the mass and charge balances, we obtain:

⇒ [H3O+] = 3.1386 E-6 M

⇒ pH = 5.503

d) 12.5 mL KOH:

at the equivalence point, there is complete salt formation, then the pH is calculated through the salt:

CH3COO- + H2O ↔ CH3COOH - OH-

∴ Kw/Ka = 1 E-14/1.75 E-5 = 5.714 E-10 = [CH3COOH]*[OH-]/[CH3COO-]

∴ [CH3COO-] = (0.025)(0.100))/(0.025+0.0125) = 0.066 M

mass balance:

⇒ 0.066 = [CH3COOH] + [CH3COO-]..........(1)

charge balance:

⇒ [K+] = [OH-] + [CH3COO-] = 0.066 M.........(2)

∴ [K+] = C CH3COO- = 0.066 M

(1) = (2):

⇒ [OH-] = [CH3COOH].......(3)

⇒ 5.714 E-10 = [OH-]² / (0.066 - [OH-])

⇒ [OH-]² + 5.714 E-10[OH-] - 3.7712 E-11 = 0

⇒ [OH-] = 6.1408 e-6 m

⇒ pOH = 5.212

⇒ pH = 14 - pOH = 8.788

d) 15.0 mL KOH:

after the equivalence point there is salt and excess base (OH-); ph is calculated from excess base:

⇒ C KOH = ((0.015)(0.200) - (0.025)(0.100)) / (0.025 + 0.015) = 0.0125 M

⇒ [OH-] ≅ C KOH = 0.0125 M

⇒ pOH = 1.903

⇒ pH = 12.097

8 0

2 years ago

How many copper(I) ions (atoms of Cu 1+ ) are in a sample of copper(I) sulfate that weighs 35.4 grams?

Keith_Richards [23]

Answer:

copper has 2+ ions in a sample of copper

5 0

2 years ago

Given that a for HCN is 6. 2×10^−10 at 25 °C. What is the value of b for cn− at 25 °C?

Kay [80]

If Ka for HCN is 6. 2×10^−10 at 25 °C, then the value of Kb for cn− at 25 °C is 1.6 × 10^(-5).

<h3>What is base dissociation constant? </h3><h3 />

The base dissociation constant (Kb) is defined as the measurement of the ions which base can dissociate or dissolve in the aqueous solution. The greater the value of base dissociation constant greater will be its basicity an strength.

The dissociation reaction of hydrogen cyanide can be given as

HCN --- (H+) + (CN-)

Given,

The value of Ka for HCN is 6.2× 10^(-10)

The correlation between base dissociation constant and acid dissociation constant is

Kw = Ka × Kb

Kw = 10^(-14)

Substituting values of Ka and Kw,

Kb = 10^(-14) /{6.2×10^(-10) }

= 1.6× 10^(-5)

Thus, the value of base dissociation constant at 25°C is 1.6 × 10^(-5).

learn more about base dissociation constant :

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4 0

2 years ago

22. Which statement best describes the use of catalytic converters in automobiles?

AysviL [449]

Answer:

B. They oxidize hydrocarbons to form less toxic gases.

Explanation:

A catalytic converter can be defined as an anti-pollution device containing a catalyst like platinum-iridium, installed in the exhaust chamber of an automobile so as to chemically convert harmful (poisonous) pollutants such as unburned hydrocarbons and carbon monoxide (CO), sulfur dioxide (S02), nitrogen oxide (NO) etc., into less harmful, poisonous or toxic chemical compounds.

This ultimately implies that, catalytic converters are typically used for converting harmful gases into less harmful, poisonous or toxic gases and molecules e.g carbon dioxide (C02) and water (H2O). This helps to prevent global warming, enhance the conservation of natural resources, as well as preserve the lives of living organisms and their natural habitat.

Hence, the statement which best describes the use of catalytic converters in automobiles is that they oxidize hydrocarbons to form less toxic gases.

3 0

2 years ago