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Bad White [126]
3 years ago
11

You are asked to prepare a ph = 4.00 buffer starting from 1.50 l of 0.0200 m solution of benzoic acid (c6h5cooh and some added s

odium benzoate salt (c6h5coona. a find the ph of the benzoic acid solution before adding the salt. b use the henderson-hasselbalck equation to derive how many moles of the salt you should add. c how many grams of the salt should you add?
Chemistry
1 answer:
sveta [45]3 years ago
5 0
The <span>henderson-hasselbalck equation is this
pH = pK + log [salt]/[acid]

We are given with
pH = 4.00
</span><span>1.50 l of 0.0200 m solution of benzoic acid

The pK for benzoic acid is
4.20

Solving for the moles of salt,
4 = 4.2 + log 1.5(0.02)/n
n =  71.62 moles
The mass is
m = 71.62 (249.2)
m = 17800 grams</span>
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Explanation:

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The chemical formula of the compound is: CoBr2•4H2O

We then need to determine the number of moles of CoBr2•4H2O since this is the only information missing for us to find molarity. Notice that the volume of the solution is already given.

We’re given the mass of CoBr2•4H2O. We can use the molar mass of CoBr2•4H2O4 to find the moles.

•The molar mass of CoBr2•4H2O is:

CoBr2•4H2O  

1 Co x 58.93 g/mol Co = 58.93 g/mol

2 Br x 79.90 g/mol Br = 159.80 g/mol

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4 O  x 16.00 g/mol O = 64.00 g/mol

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                           Sum = <u>290.79 g/ mo</u>

The moles of CoBr2•4H2O is:

= 10.0 g CoBr2•4H2O x  \frac{ 1 mol  CoBr_2 . 4H_2O}{290.79 g CoBr_2 .  4H_2O}

= <u>0.0344  mol CoBr2•4H</u>

We know that the volume of the solution is 450 mL.

We can now calculate for molarity:

Convert mL to L → 1 mL = 10-3 L

Formula:

Molarity (M)= Mole of solute / Liters of solution

= 0.0344  mol CoBr2•4H  / 450 mL x 1 ml / 10^ -3 L

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