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Bad White [126]
3 years ago
11

You are asked to prepare a ph = 4.00 buffer starting from 1.50 l of 0.0200 m solution of benzoic acid (c6h5cooh and some added s

odium benzoate salt (c6h5coona. a find the ph of the benzoic acid solution before adding the salt. b use the henderson-hasselbalck equation to derive how many moles of the salt you should add. c how many grams of the salt should you add?
Chemistry
1 answer:
sveta [45]3 years ago
5 0
The <span>henderson-hasselbalck equation is this
pH = pK + log [salt]/[acid]

We are given with
pH = 4.00
</span><span>1.50 l of 0.0200 m solution of benzoic acid

The pK for benzoic acid is
4.20

Solving for the moles of salt,
4 = 4.2 + log 1.5(0.02)/n
n =  71.62 moles
The mass is
m = 71.62 (249.2)
m = 17800 grams</span>
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Aa we know that, 125mL of 0.06M Pb(NO3)2 is mixed with 75.0 ml of 0.0200 m NaCl.

Given, T = 25°C.

<h3>Chemical equation:</h3>

Pb(NO3)2 + NaCl ---- NaNO3 + PbCl2

PbCl2 in aqueous solution split into following ions

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Q = [Pb(+2)] [Cl-]^2

The Concentration of Pb(+2) ions and Cl- ions can be calculated as

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[Cl-] = 0.02 × 75/200

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By substituting all the values, we get

[0.0375] [0.0075]^2

= 2.11 × 10^(-6).

Thus, we calculated that the value of Q for 125.0 ml of 0.0500 m Pb(NO3)2 is mixed with 75.0 ml of 0.0200 m NaCl at 25°C is 2.11 × 10^(-6).

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