Arrhenius' equation relates the dependence of rate constant of a chemical reaction to the temperature. The equation below is the Arrhenius equation

where k is the rate constant, T is the absolute temperature. As the temperature of the system increases, the rate constant also increases and vice versa.
Answer:
(a) 
(b) 
Explanation:
(a) The surface current density of a conductor is the current flowing per unit length of the conductor.

Considering a wire, the current is uniformly distributed over the circumferenece of the wire.

The radius of the wire = a

The surface current density 
(b) The current density is inversely proportional
......(1)
k is the constant of proportionality

........(2)
substituting (1) into (2)





substitute 

Answer:
The lone pair of electrons occupy more space because the electrostatic force becomes weaker.
Explanation:
When there is a bond pair of electrons in the 2 positively charged the atomic nuclei draw the electron density towards them, thereby reducing the bond diameter.
In the case of the lone pair, only 1 nucleus is present, and the enticing electrostatic force becomes weaker and the intensity of the electrons will be increases. Therefore, the lone pair occupies more space than the pair of bonds.