The number of electrons, which are present in the nonbonding π molecular orbital of the allyl anion is "0".
Anions, cations, but also allylic radicals have always been frequently mentioned as reaction intermediates. Each one has three adjacent
-hybridized carbon centers, and they all rely on resonance for stability. Two resonance structures would be used to present each species, with the charge as well as unpaired electron scattered across both the 1,3 and 0 positions.
The Aufbau principle states that these orbitals would fill up based on the order of stability, therefore a typical pi bond, will have 2 electrons in the Pi orbital as well as zero in the Pi* orbital.
Therefore, the correct answer will be option (d)
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Answer:
33.3 kg of air
Explanation:
This is a problem of conversion unit.
Density is mass / volume
Therefore we have to calculate the volume in the room, to be multiply by density. That answer will be the mass of air.
Volume of the room → 9 ft . 11 ft . 10 ft = 990 ft³
Density is in g/L, therefore we have to convert the ft³ to dm³ (1 dm³ = 1L)
990 ft³ . 28.3 dm³ / 1ft³ = 28017 dm³ → 28017 L
This is the volume of the room, if we replace it in the density formula we can know the mass of air in g.
1.19 g/L = Mass of air / 28017 L
Mass of air = 28017 L . 1.19 g/L → 33340 g of air
Finally, let's convert the mass in g to kg → 33340 g . 1kg / 1000 g = 33.3 kg
The radius of a chlorine ion is larger than the radius of a chlorine atom because the effective nuclear charge decreases, therefore the inward force decreases, increasing the ionic radius.
Answer:
The major product is 2-methyl-2-pentene [ CH₃-CH₂-CH=C(CH₃)₂ ] and a minor product 2-methyl-1-pentene [ CH₃-CH₂-CH₂-C(CH₃)=CH₂ ].
Explanation:
Dehydration reaction is a reaction in which a molecule loses a water molecule in the presence of a dehydrating agent like sulfuric acid (H₂SO₄).
<u>Dehydration reaction of 2-methyl-2-pentanol</u> gives a major product 2-methyl-2-pentene and a minor product 2-methyl-1-pentene.
CH₃-CH₂-CH₂-C(CH₃)₂-OH (2-methyl-2-pentanol)→ CH₃-CH₂-CH=C(CH₃)₂ (2-methyl-2-pentene, major) + CH₃-CH₂-CH₂-C(CH₃)=CH₂ (2-methyl-1-pentene, minor)
<u>Since more substituted alkene is more stable than the less substituted alkene. So, the trisubstituted alkene, 2-methyl-2-pentene is more stable than the disubstituted alkene, 2-methyl-1-pentene.</u>
<u>Therefore, the trisubstituted alkene, 2-methyl-2-pentene is the major product and the disubstituted alkene, 2-methyl-1-pentene is the minor product.</u>
Answer:
Hypsochromic shift.
The second solvent is more polar.
Explanation:
Compound A + Solvent 1 = red
Compound A + Solvent 2 = orange
Since orange has a smaller wavelength than red, the electronic transition observed when the compound A is dissolved in solvent 2 has a higher energy.
A band transition to a lower wavelength and higher energy is called a hypsochromic shift.
The change in the color due to the solvent is called solvatochromism. Usually, when the hypsochromic shift is observed (negative solvatochromism) it means that the solvent is more polar.