How many miles of co2 are produced if 5.0 moles of c10h22 react with an excess of o2?
1 answer:
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Answer : The value of for this reaction is 36.18 kJ
Explanation :
First law of thermodynamic : It states that the energy can not be created or destroyed, it can only change or transfer from one state to another state.
As per first law of thermodynamic,
where,
= internal energy of the system
q = heat added or rejected by the system
w = work done
As we are given that:
q = 38.65 kJ
w = -2.47 kJ (system work done on surrounding)
Now put all the given values in the above expression, we get:
Therefore, the value of for this reaction is 36.18 kJ
Answer:
B. First order, Order with respect to C = 1
Explanation:
The given kinetic data is as follows:
A + B + C → Products
[A]₀ [B]₀ [C]₀ Initial Rate (10⁻³ M/s)
1. 0.4 0.4 0.2 160
2. 0.2 0.4 0.4 80
3. 0.6 0.1 0.2 15
4. 0.2 0.1 0.2 5
5. 0.2 0.2 0.4 20
The rate of the above reaction is given as:
where x, y and z are the order with respect to A, B and C respectively.
k = rate constant
[A], [B], [C] are the concentrations
In the method of initial rates, the given reaction is run multiple times. The order with respect to a particular reactant is deduced by keeping the concentrations of the remaining reactants constant and measuring the rates. The ratio of the rates from the two runs gives the order relative to that reactant.
Order w.r.t A : Use trials 3 and 4
Order w.r.t B : Use trials 2 and 5
Order w.r.t C : Use trials 1 and 2
we know that x = 1 and y = 2, substituting the appropriate values in the above equation gives:
z = 1
Therefore, order w.r.t C = 1