The boiling point of a substance in City A is found to be 145 degrees celcius. The boiling point of the same substance in City B
1 answer:
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Explanation:
Upon dissolution of KCl heat is generated and temperature of the solution raises.
Therefore, heat generated by dissolving 0.25 moles of KCl will be as follows.
= 4.31 kJ
or, = 4310 J (as 1 kJ = 1000 J)
Mass of solution will be the sum of mass of water and mass of KCl.
Mass of Solution = mass of water + (no. of moles of KCl × molar mass)
= 200 g +
= 200 g + 13.625 g
= 213.625 g
Relation between heat, mass and change in temperature is as follows.
Q =
where, C = specific heat of water =
Therefore, putting the given values into the above formula as follows.
Q =
4310 J =
Thus, we can conclude that rise in temperature will be .
Answer:
All of the above.
Explanation:
In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.
When a solution is non ideal then it shows positive or negative deviation.
Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is and vapour pressure of component B is
.
= Vapour pressure of component A in pure form
= Vapour pressure of component B in pure form
=Mole fraction of component A
=Mole fraction of component B
The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.
,
Therefore,
Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.
Hence, option a,b,c and d are true.