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Oxana [17]
3 years ago
12

The initial activity of 37Ar is 8540 disintegrations per minute. After 10.0 days, the activity is 6990 disintegrations per minut

e. what is the activity after 47.2 days?​
Chemistry
1 answer:
mylen [45]3 years ago
8 0

Answer:

Approximately 3318 disintegrations per minute.

Explanation:

The activity A of a radioactive decay at time t can be found with the following equation:

\displaystyle A(t) = A_0 \cdot \mathrm{e}^{-\lambda\cdot t}.

In this equation,

  • \mathrm{e} is the natural base. \mathrm{e}\approx 2.71828.
  • A_0 is the initial activity of the decay. For this question, A_0 = \rm 8540\; min^{-1}.
  • The decay constant \lambda of this sample needs to be found.

The decay constant here can be found using the activity after 10 days. As long as both times are in the same unit (days in this case,) conversion will not be necessary.

A(10) = A_0\cdot \mathrm{e}^{\rm -\lambda \times 10\;day}= (\mathrm{8540\; min^{-1}})\cdot \mathrm{e}^{\rm -\lambda \times 10\;day}.

A(10) = \rm 6690\; min^{-1}.

\displaystyle \frac{\rm 6690\; min^{-1}}{\mathrm{8540\; min^{-1}}} = \mathrm{e}^{\rm -\lambda \times 10\;day}

Apply the natural logarithm to both sides of this equation.

\displaystyle \ln{\left(\frac{\rm 6690\; min^{-1}}{\mathrm{8540\; min^{-1}}}\right)} = \ln{\left(\mathrm{e}^{\rm -\lambda \times 10\;day}\right)}.

\displaystyle \rm -\lambda \cdot (10\;day) = \ln{\left(\frac{\rm 6690\; min^{-1}}{\mathrm{8540\; min^{-1}}}\right)}.

\displaystyle \rm \lambda= \rm \frac{\displaystyle \ln{\left(\frac{\rm 6690\; min^{-1}}{\mathrm{8540\; min^{-1}}}\right)}}{-10 \; day} \approx 0.0200280\; day^{-1}.

Note that the unit of the decay constant \lambda is \rm day^{-1} (the reciprocal of days.) The exponent -\lambda \cdot t should be dimensionless. In other words, the unit of t should also be days. This observation confirms that there's no need for unit conversion as long as the two times are in the same unit.

Apply the equation for decay activity at time t to find the decay activity after 47.2 days.

\displaystyle \begin{aligned}A(t)& = A_0 \cdot \mathrm{e}^{-\lambda\cdot t}\\&\approx \rm \left(8540\; min^{-1}\right)\cdot \mathrm{e}^{-0.0200280\; day^{-1}\times 47.2\;day}\\&\approx \rm 3318\; min^{-1}\end{aligned}.

By dimensional analysis, the unit of activity here should also be disintegrations per minute. The activity after 47.2 days will be approximately 3318 disintegrations per minute.

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The following data were collected for the rate of disappearance of NO in the reaction 2NO(g)+O2(g)→2NO2(g)::
Anit [1.1K]

Answer:

a) The rate law is: v = k[NO]² [O₂]

b) The units are: M⁻² s⁻¹

c) The average value of the constant is: 7.11 x 10³ M⁻² s⁻¹

d) The rate of disappearance of NO is 0.8 M/s

e) The rate of disappearance of O₂ is 0.4 M/s

Explanation:

The experimental rates obtained can be expressed as follows:

v1 = k ([NO]₁)ᵃ ([O₂]₁)ᵇ = 1.41 x 10⁻² M/s

v2 = k ([NO]₂)ᵃ ([O₂]₂)ᵇ = 5.64 x 10⁻² M/s

v3 = k ([NO]₃)ᵃ ([O₂]₃)ᵇ = 1.13 x 10⁻¹ M/s

where:

k = rate constant

[NO]₁ = concentration of NO in experiment 1

[NO]₂ = concentration of NO in experiment 2

[NO]₃ = concentration of NO in experiment 3

[O₂]₁ = concentration of O₂ in experiment 1

[O₂]₂ = concentration of O₂ in experiment 2

[O₂]₃ = concentration of O₂ in experiment 3

a and b = order of the reaction for each reactive respectively.

We can see these equivalences:

[NO]₂ = 2[NO]₁

[O₂]₂ = [O₂]₁

[NO]₃ = [NO]₂

[O₂]₃ = 2[O₂]₂

So, v2 can be written in terms of the concentrations used in experiment 1 replacing [NO]₂ for 2[NO]₁ and [O₂]₂ by [O₂]₁ :

v2 = k (2 [NO]₁)ᵃ ([O₂]₁)ᵇ

If we rationalize v2/v1, we will have:

v2/v1 = k *2ᵃ * ([NO]₁)ᵃ * ([O₂]₁)ᵇ / k * ([NO]₁)ᵃ * ([O₂]₁)ᵇ (the exponent "a" has been distributed)

v2/v1 = 2ᵃ

ln(v2/v1) = a ln2

ln(v2/v1) / ln 2 = a

a = 2

(Please review the logarithmic properties if neccesary)

In the same way, we can find b using the data from experiment 2 and 3 and writting v3 in terms of the concentrations used in experiment 2:

v3/v2 = k ([NO]₂)² * 2ᵇ * ([O₂]₁)ᵇ / k * ([NO]₂)² * ([O₂]₂)ᵇ

v3/v2 = 2ᵇ

ln(v3/v2) = b ln 2

ln(v3/v2) / ln 2 = b

b = 1

Then, the rate law for the reaction is:

<u>v = k[NO]² [O₂]</u>

Since the unit of v is M/s and the product of the concentrations will give a unit of M³, the units of k are:

M/s = k * M³

M/s * M⁻³ = k

<u>M⁻² s⁻¹ = k </u>

To obtain the value of k, we can solve this equation for every experiment:

k = v / [NO]² [O₂]

for experiment 1:

k = 1.41 x 10⁻² M/s / (0.0126 M)² * 0.0125 M = 7.11 x 10³ M⁻² s⁻¹

for experiment 2:

k = 7.11 x 10³ M⁻² s⁻¹

for experiment 3:

k = 7.12 x 10³ M⁻² s⁻¹

The average value of k is then:

(7.11 + 7.11 + 7.12) x 10³ M⁻² s⁻¹ / 3 = <u>7.11 x 10³ M⁻² s⁻¹ </u>

The rate of the reaction when [NO] = 0.0750 M and [O2] =0.0100 M is:

v = k [NO]² [O₂]

The rate of the reaction in terms of the disappearance of NO can be written this way:

v = 1/2(Δ [NO] / Δt) (it is divided by 2 because of the stoichiometric coefficient of NO)

where (Δ [NO] / Δt) is the rate of disappearance of NO.

Then, calculating v with the data provided by the problem:

v = 7.11 x 10³ M⁻² s⁻¹ * (0.0750M)² * 0.0100M = 0.4 M/s

Then, the rate of disappearance of NO will be:

2v = Δ [NO] / Δt = <u>0.8 M/s</u>

The rate of disappearance of O₂ has to be half the rate of disappearance of NO because two moles of NO react with one of O₂. Then Δ [O₂] / Δt = <u>0.4 M/s</u>

With calculations:

v = Δ [O₂] / Δt = 0.4 M/s (since the stoichiometric coefficient is 1, the rate of disappearance of O₂ equals the rate of the reaction).

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