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Alona [7]
3 years ago
13

Which equation represents the combined gas law?

Chemistry
1 answer:
Keith_Richards [23]3 years ago
8 0
<span>((P1V1/T1)=(P2V2/T2))</span>
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A 100.0 mL solution containing 0.864 g of maleic acid (MW=116.072 g/mol) is titrated with 0.276 M KOH. Calculate the pH of the s
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Answer:

pH = 1.32

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                 H₂M + KOH ------------------------ HM⁻ + H₂O + K⁺

This problem involves a weak diprotic acid which we can solve by realizing they amount  to buffer solutions.  In the first  deprotonation if all the acid is not consumed we will have an equilibrium of a wak acid and its weak conjugate base. Lets see:

So first calculate the moles reacted and produced:

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it is clear that the maleic acid will not be completely consumed, hence treat it as an equilibrium problem of a buffer solution.

moles H₂M left = 0.074 - 0.015 = 0.059

moles HM⁻ produced = 0.015

Using the Henderson - Hasselbach equation to solve for pH:

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For polyprotic acids the second or third deprotonation contribution to the pH when there is still unreacted acid ( Maleic in this case) unreacted.

           

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7 0
3 years ago
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