Delta E = Ef - Ei
E = energy , h = plank constant , v = frequency
h= 6.626 * 10 ^-34 j*s , T = 10 ^ 12 , v = 74 * 10 ^12 Hz , Hz = s^-1
E = ( 6.626 * 10^ -34 j*s) ( 74 * 10 ^ 12 s^ -1 ) = 4.90 * 10 ^ -20 J
Delta E = Ef - Ei
-4.90 * 10 ^ -20 J = -2.18 * 10 ^ -18J ( 1/4 ^2 - 1/x ^2)
0.0225 = 0.0625 - ( 1/x ^ 2)
0.225 - 0.0625 = - 1/ x ^ 2
- 0.0400 = - 1/x ^2 = -1 / - 0.0400 = x^2
25 = x^2
x = 5
Answer:
K8S4O16 or K8(SO4)4 depending on if the SO4 is supposed to represent sulfate or not
Explanation:
Find the molar mass of K2SO4 first:
2K + S + 4O ≈ 174 g/mol
Divide the goal molar mass of 696 by the molar mass of the empirical formula:
696 / 174 = 4
This means you need to multiply everything in the empirical formula by 4:
K2SO4 --> K8S4O16 or K8(SO4)4 depending on if the SO4 is for sulfate or not
Alkenes on reacting with ozone results in the formation of ozonide which undergo reductive cleavage in presence of dimethyl sulfide to form carbonyl compounds (aldehyde or ketone). Whereas in presence of hydrogen peroxide it undergoes oxidative cleavage to form carboxylic acids or ketones.
Since, A alkene yields 4-heptanone only on treatment with ozone and DMS thus, it implies that both the chains on the side of the double-bond are similar the product is 4-heptanone that means the double bond is present between the chains at the 4th carbon. Therefore the structure of compound A is 4,5-dipropyloct-4-ene.
The reaction is as shown in the image.
The reaction of A with m-CPBA (meta-perchlorobenzoic acid) followed by aqueous acid
is shown in the image.
m-CPBA (meta-perchlorobenzoic acid) is a peracid and forms epoxides on reacting with alkenes.