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Answer : The equilibrium concentration of in the trial solution is
Explanation :
First we have to calculate the initial moles of and
.
and,
The given balanced chemical reaction is,
Since 1 mole of reacts with 1 mole of
to give 1 mole of
The limiting reagent is,
So, the number of moles of = 0.0020 mmole
Now we have to calculate the concentration of .
Using Beer-Lambert's law :
where,
A = absorbance of solution
C = concentration of solution
l = path length
= molar absorptivity coefficient
and l are same for stock solution and dilute solution. So,
For trial solution:
The equilibrium concentration of is,
= 0.00050 M
Now calculate the .
Now calculate the concentration of .
Therefore, the equilibrium concentration of in the trial solution is
Answer:
1) 2Al + 6HCl ⟶ 2AlCl₃ + 3H₂
Fe + 2HCl ⟶ FeCl₂ + H₂
2) Cu = 2.5 g; Al = 3.5 g; Fe = 4.0 g
Explanation:
1) Possible reactions
2Al + 6HCl ⟶ 2AlCl₃ + 3H₂
Fe + 2HCl ⟶ FeCl₂ + H₂
2) Mass of each metal
a) Mass of Cu
The waste was the unreacted copper.
Mass of Cu = 2.5 g
b) Masses of Al and Fe
We have two relations :
Mass of Al + mass of Fe = 10 g - 2.5 g = 7.5 g
H₂ from Al + H₂ from Fe = 6.38 L at NTP
i) Calculate the moles of H₂
NTP is 20 °C and 1 atm.
(ii) Solve the relationship
Let x = mass of Al. Then
7.5 - x = mass of Fe
Moles of Al = x/27
Moles of Fe = (7.5 - x)/56
Moles of H₂ from Al = (3/2) × Moles of Al = (3/2) × (x/27) = x /18
Moles of H₂ from Fe = (1/1) × Moles of Fe = (7.5 - x)/56
∴ x/18 + (7.5 - x)/56 = 0.2652
56x + 18(7.5 - x) = 267.3
56x + 135 - 18x = 267.3
38x = 132.3
x = 3.5 g
Mass of Al = 3.5 g
Mass of Fe = 7.5 g - 3.5 g = 4.0 g
The masses of the metals are Cu = 2.5 g; Al = 3.5 g; Fe = 4.0 g