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Misha Larkins [42]
4 years ago
8

How many milliliters of an aqueous solution of 0.170 M ammonium carbonate is needed to obtain 16.1 grams of the salt

Chemistry
1 answer:
Citrus2011 [14]4 years ago
5 0

There will be needed 982.35 mL of solution to obtain 16.1 grams of the salt.There will be needed mL of

Why?

In order to calculate how many milliliters are needed to obtain 16.1 grams of the salt given its concentration, we first need to find its chemical formula which is the following:

(NH_{4})2CO_{3}

Now that we know the chemical formula of the substance, we need to find its molecular mass. We can do it by the following way:

N_{2}=14g*2=28g\\\\2H_{4}=2*1g*4=8g\\\\C=12.01g*1=12.01g\\\\O_{3}=15.99g*3=47.97g

We have that the molecular mass of the substance will be:

MolecularMass=\frac{28g+8g+12.01g+47.97g}{mol}=95.98\frac{g}{mol}

Therefore, knowing the molecular mass of the substance, we need to calculate how many mols represents 16.1 grams of the same substance, we can do it by the following way:

mol_{(NH_{4})2CO_{3}=\frac{mass_{(NH_{4})2CO_{3}}}{molarmass_{(NH_{4})2CO_{3}}}

mol_{(NH_{4})2CO_{3}=\frac{16.1g}{95.98\frac{g}{mol}}=0.167mol

Finally, if we need to calculate how many milliliters are needed, we need to use the following formula:

M=\frac{moles_{solute}}{volume_{solution}}

M=\frac{moles_{solute}}{volume_{solution}}\\\\volume_{solution}=\frac{moles_{solute}}{M}

Now, substituting and calculating, we have:

volume_{solution}=\frac{0.167mol}{0.170\frac{mol}{L}}\\\\volume_{solution}=0.982L=0.982L*1000=982.35mL

Henc, there will be needed 982.35 mL of solution to obtain 16.1 grams of the salt.

Have a nice day!

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The complete question is shown on the first uploaded image

Answer:

a) The activation energy is 124.776\frac{kJ}{mole}

b) The frequency factor is 1.77 ×10^{18}

c) The rate constant is 0.00033 (\frac{dm^{3} }{mole} )^{2}\frac{1}{s}

Explanation:

From the question the elementary reaction for A and B is given as

      2A + B → 4C

The rate equation the elementary reaction is

      -r_{A} = k[A]^{2}[B]

            =  k[2]^{2}[1.5]

            = 6k

     k = \frac{-r_{A} }{6}

      When temperature changes, the rate constant change an this causes the rate of reaction to change as shown on the second uploaded image.

The relationship between temperature and rate constant can be deduced from these equation

                    k = Aexp(-\frac{E_{a} }{RT} )

             taking ln of both sides we have

                   lnk =ln A - (\frac{E_{a} }{R}) \frac{1}{T}

        Considering the graph for the rate constant ln k and (\frac{1}{T} ) the slope from the equation is -(\frac{E_{a} }{R}) and the intercept is ln A

From the given table we can generate another table using the equation above as shown on the third uploaded image

The graph of ln k  vs (\frac{1}{T} )  is shown on the fourth uploaded image

  From the graph we can see that the slope is -(\frac{E_{a} }{R} ) = - 15008

Now we can obtain the activation energy E_{a} by making it the subject in the equation also generally R which is the gas constant is 8.145 \frac{J}{kmole}

                E_{a}  = 15008 ×  8,3145\frac{J}{molK}  

                     = 124\frac{KJ}{mole}

    Hence the activation energy is = 124\frac{KJ}{mole}

b) From the graph its intercept is ln A = 42.019

                                                          A = exp(42.019)

                                                             =1.77 × 10^{18}

Hence the frquency factor A is  =1.77 × 10^{18}

c) From the equation of rate constant

                                          lnk =ln A - (\frac{E_{a} }{R}) \frac{1}{T}

We have

                ln k = 42.019 - 15008 * (\frac{1}{300} )

                      k = 0.00033(\frac{dm^{3} }{mole} )^{2} \frac{1}{s}

Hence the rate constant is k = 0.00033(\frac{dm^{3} }{mole} )^{2} \frac{1}{s}    

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