1) in periodic acid (HIO₄), iodine has oxidation number +7, hydrogen has oxidation number +1, oxygen has -2, compound has neutral charge:
+1 + x + 4 · (-2) = 0.
x = +7.
2) in molecule of iodine (I₂), iodine has oxidation number 0, because iodine is nonpolar molecule.
3) in sodium iodide (NaI), iodine has oxidation number -1, sodium has oxidation number +1:
+1 + x = 0.
x = -1.
4) in iodic acid (HIO₃), iodine has oxidation number +5, hydrogen has oxidation number +1, oxygen has -2, compound has neutral charge:
+1 + x + 3 · (-2) = 0.
x = +5.
Answer:
Sprinkling of powder on the carom board <u>reduces</u> friction.
The rate of disappearance of chlorine gas : 0.2 mol/dm³
<h3>Further explanation</h3>
The reaction rate (v) shows the change in the concentration of the substance (changes in addition to concentrations for reaction products or changes in concentration reduction for reactants) per unit time.
For reaction :

The rate reaction :
![\tt -\dfrac{1}{a}\dfrac{d[-A]}{dt}= -\dfrac{1}{b}\dfrac{d[-B]}{dt}=\dfrac{1}{c}\dfrac{d[C]}{dt}=\dfrac{1}{d}\dfrac{d[D]}{dt}](https://tex.z-dn.net/?f=%5Ctt%20-%5Cdfrac%7B1%7D%7Ba%7D%5Cdfrac%7Bd%5B-A%5D%7D%7Bdt%7D%3D%20-%5Cdfrac%7B1%7D%7Bb%7D%5Cdfrac%7Bd%5B-B%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bc%7D%5Cdfrac%7Bd%5BC%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bd%7D%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D)
Reaction for formation CCl₄ :
<em>CH₄+4Cl₂⇒CCl₄+4HCl</em>
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From equation, rate of reaction = rate of formation CCl₄ = 0.05 mol/dm³
Rate of formation of CCl₄ = reaction rate x coefficient of CCCl₄
0.05 mol/dm³ = reaction rate x 1⇒reaction rate = 0.05 mol/dm³
The rate of disappearance of chlorine gas (Cl₂) :
Rate of disappearance of Cl₂ = reaction rate x coefficient of Cl₂
Rate of disappearance of Cl₂ = 0.05 x 4 = 0.2 mol/dm³