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3 years ago

Which of the following statements correctly expresses Collision Theory

1 answer:

3 0

According to a source, the options that fits the question is reactants collide with reactants to form activated complex that separates into products. This clearly suggest the collision theory.

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Consider the reaction given below.

Drupady [299]

Answer:

K = 0.167 s⁻¹

Explanation:

1) Rate law, at a given temperature:

Since all the data are obtained at the same temperature, the equilibrium constant is the same.

Since only reactants A and B participate in the reaction, you assume that the form of the rate law is:

r = K [A]ᵃ [B]ᵇ

2) Use the data from the table

Since the first and second set of data have the same concentration of the reactant A, you can use them to find the exponent b:

r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s

r₂ = (1.50)ᵃ (2.50)ᵇ = 2.50 × 10⁻¹ M/s

Divide r₂ by r₁: [ 2.50 / 1.50] ᵇ = 1 ⇒ b = 0

Use the first and second set of data to find the exponent a:

r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s

r₃ = (3.00)ᵃ (1.50)ᵇ = 5.00 × 10⁻¹ M/s

Divide r₃ by r₂: [3.00 / 1.50]ᵃ = [5.00 / 2.50]

2ᵃ = 2 ⇒ a = 1

3) Write the rate law

r = K [A]¹ [B]⁰ = K[A]

This means, that the rate is independent of reactant B and is of first order respect reactant A.

4) Use any set of data to find K

With the first set of data

r = K (1.50 M) = 2.50 × 10⁻¹ M/s ⇒ K = 0.250 M/s / 1.50 M = 0.167 s⁻¹

Result: the rate constant is K = 0.167 s⁻¹

6 0

3 years ago

Question 2 of 5 What do you know about a substance it you know its temperature?

notka56 [123]

One may know how close the molecules within the substances are packed together. Hot substances have molecules that are farther apart, cold substances have molecules that are more compact/closer together.

5 0

3 years ago

Read 2 more answers

Two molecules that can cross a lipid bilayer without help from membrane proteins are o2 and co2. what property allows this to oc

Dennis_Churaev [7]

Two molecules that can cross a lipid bilayer without help from membrane proteins are oxygen and carbon dioxide. The property that allows this to happen is that both oxygen and carbon dioxide molecules are nonpolar which means that they can pass easily through the hydrophobic part of the membrane. The lipid bilayer is present in all cell membranes. It consists of two layers of the fat cells which are arranged into two sheets. It functions as a barrier which marks the boundaries of the cell. The inner part of a lipid bilayer is nonpolar since it is composed of the hydrophobic end of the phospholopids.

4 0

3 years ago

Question 6

ss7ja [257]

Answer:

He is probably studying Geomorphology.

Explanation:

Geology is the science that studies the composition, structure, dynamics, and history of planet Earth, the processes by which it has evolved including everything that has to do with its natural resources and with this the processes that affect the surface, and therefore, the environment.

Geomorphology is a branch of geosciences, more specifically geography and geology. One of his most interesting models explains the ways in which the earth's surface is the result of a consistent dynamic balance.

3 0

3 years ago

50.0 mL solution of 0.160 M potassium alaninate ( H 2 NC 2 H 5 CO 2 K ) is titrated with 0.160 M HCl . The p K a values for the

scZoUnD [109]

Answer:

a) 6.12

b) 1.87

Explanation:

At the onset of the equivalence point (i.e the first equivalence point); alaninate is being converted to alanine.

$H_2NC_2H_5CO^-_2$ $+$ $H^+$ ------> $H_3}^+NC_2H_5CO^-_2$

1 mole of alaninate react with 1 mole of acid to give 1 mole of alanine;

therefore 50.0 mL of 0.160 M alaninate required 50.0 mL of 0.160M HCl to reach the first equivalence point.

The concentration of alanine can be gotten via the following process as shown below;

$[H_3}^+NC_2H_5CO^-_2]$ = $\frac{initial moles of alaninate}{total volume}$

$[H_3}^+NC_2H_5CO^-_2]$ = $\frac{(50.0mL)*(0.160M)}{(50.0mL+50.0mL)}$

$[H_3}^+NC_2H_5CO^-_2]$ = $\frac{8}{100mL}$

$[H_3}^+NC_2H_5CO^-_2]$ = 0.08 M

Alanine serves as an intermediary form, however the concentration of $H^+$ and the pH can be determined as follows;

$[H^+]$ = $\sqrt{\frac{K_{a1}K_{a2}{[H_3}^+NC_2H_5CO^-_2]+K_{a1}K_w}{ K_{a1}{[H_3}^+NC_2H_5CO^-_2] } }$

$[H^+]$ = $\sqrt{\frac{ (10^{-pK_{a1})}(10^{-pK_{a2})}(0.08)+(10^{-pK_{a1})}(1.0*10^{-14})} {(10^{-pK_{a1}})+(0.08)} }$

$[H^+]$ = $\sqrt{\frac{ (10^{-2.344})(10^{-9.868})(0.08)+(10^{-2.344})(1.0*10^{-14})} {(10^{-2.344})+(0.08)} }$

$[H^+]$ = $7.63*10^{-7}M$

pH = - log $[H^+]$

pH = $-log[7.63*10^{-7}]$

pH= 6.12

Therefore, the pH of the first equivalent point = 6.12

b) At the second equivalence point; all alaninate is converted into protonated alanine.

$H_2NC_2H_5CO^-_2$ $+$ $H^+$ -----> $H^+_3NC_2H_5CO^-_2$

$H^+_3NC_2H_5CO^-_2$ $+$ $H^+$ -----> $H^+_3NC_2H_5CO_2H$

Here; we have a situation where 1 mole of alaninate react with 2 moles of acid to give 1 mole of protonated alanine;

Moreover, 50.0 mL of 0.160 M alaninate is needed to produce 100.0mL of 0.160 M HCl in order to achieve the second equivalence point.

Thus, the concentration of protonated alanine can be determined as:

$[H^+_3NC_2H_5CO_2H]$ = $\frac{initial moles of alaninate}{total volume}$

$[H^+_3NC_2H_5CO_2H]$ = $\frac{(50.0mL)*(0.160M)}{(50.0mL+100.0mL)}$

$[H^+_3NC_2H_5CO_2H]$ = $\frac{8}{150}$

$[H^+_3NC_2H_5CO_2H]$ = 0.053 M

The pH at the second equivalence point can be calculated via the dissociation of protonated alanine at equilibrium which is represented as:

$H^+_3NC_2H_5CO_2H$ ⇄ $H^+_3NC_2H_5CO^-_2$ $+$ $H^+$

(0.053 - x) x x

$K_{a1}$ = $\frac{[H^+] [H^+_3NC_2H_5CO^-_2]}{[H^+_3NC_2H_5CO_2H]}$

$10^{-PK_{a1}}$ = $\frac{x*x}{(0.053-x)}$

$10^{-2.344} =\frac{x^2}{(0.053-x)}$

$0.00453 = \frac{x^2}{(0.053-x)}$

$0.00453(0.053-x) =x^2$

$x^2+0.00453x-(2.4009*10^{-4})$

Using quadratic equation formula;

$\frac{-b+/-\sqrt{b^2-4ac} }{2a}$

we have:

$\frac{-0.00453+\sqrt{(0.00453)^2-4(1)(-2.4009*10^{-4})} }{2(1)}$ OR $\frac{-0.00453-\sqrt{(0.00453)^2-4(1)(-2.4009*10^{-4})} }{2(1)}$

= 0.0134 OR -0.0179

So; we go by the positive integer which says

x = 0.0134

So $[H^+]=[H_3^+NC_2H_5CO^-_2]= 0.0134 M$

pH = $-log[H^+]$

pH = $-log[0.0134]$

pH = 1.87

Thus, the pH of the second equivalent point = 1.87

3 0

3 years ago