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lina2011 [118]
3 years ago
13

When 4.31 g of a nonelectrolyte solute is dissolved in water to make 635 mL of solution at 28 °C, the solution exerts an osmotic

pressure of 945 torr. What is the molar concentration of the solution?
Chemistry
1 answer:
blondinia [14]3 years ago
3 0

Answer:

Molar concentration is 0.050 M

Explanation:

Osmotic pressure -

Osmotic pressure is pressure applied  to stop the flow of solvent across a semipermeable membrane, from its high concentration to  its low concentration , it is a type of colligative property , i.e. , it depends on the number of moles of solute.

Osmotic pressure can be calculated from the formula -

π = CRT

π = Osmotic pressure ( in atm )

C = molarity of the solution

R = universal gas constant ( 0.082 L.atm / K.mol )

T = temperature ( Kelvin )

From the question ,

π = 945 torr

since,

760 torr = 1 atm

1 torr = 1 / 760 atm

945 torr = 1 / 760 * 945 atm

945 torr = 1.24 atm

Temperature = T = 28°C

(adding 273 To °C to convert it to K)

T = 28 + 273 = 301 K

Using the equation of osmotic pressure,

π = CRT

C = π / RT

putting the

C = 1.24 atm / 0.082 L.atm / K.mol * 301 K

C = 1.24 / 24.68

C = 0.050 M

Hence,

The Molar concentration is 0.050 M.  

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Answer : The correct option is, (A) AlCl_3

Explanation :

Van't Hoff factor : It is defined as the ratio of the experimental value of the colligative property to the calculated value of the colligative property.

We can determine the van't Hoff factor by the association and dissociation of the compound.

(A) AlCl_3

It is an electrolyte that dissociates to give aluminum ion and chloride ion.

The dissociation of AlCl_3 will be,

AlCl_3\rightarrow Al^{3+}+3Cl^{-}

So, Van't Hoff factor = Number of solute particles = Al^{3+}+3Cl^{-} = 1 + 3 = 4

(B) KI

It is an electrolyte that dissociates to give potassium ion and iodide ion.

The dissociation of KI will be,

KI\rightarrow K^{+}+I^{-}

So, Van't Hoff factor = Number of solute particles = K^{+}+I^{-} = 1 + 1 = 2

(C) CaCl_2

It is an electrolyte that dissociates to give calcium ion and chloride ion.

The dissociation of CaCl_2 will be,

CaCl_2\rightarrow Ca^{2+}+2Cl^{-}

So, Van't Hoff factor = Number of solute particles = Ca^{2+}+2Cl^{-} = 1 + 2 = 3

(D) MgSO_4

It is an electrolyte that dissociates to give magnesium ion and sulfate ion.

The dissociation of MgSO_4 will be,

MgSO_4\rightarrow Mg^{2+}+SO_4^{2-}

So, Van't Hoff factor = Number of solute particles = Mg^{2+}+SO_4^{2-} = 1 + 1 = 2

(E) Non-electrolyte

The dissociation non-electrolyte is not possible. So, the Van't Hoff factor will always be, 1.

Hence, the highest van't Hoff factor of solute is, AlCl_3

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The answer to your question is below

Explanation:

1.-

a) Look for the mass number of Gold in the periodic table

Mass number = 197 g

Use proportions to answer this question

                          197 g of gold ------------- 6.023 x 10 ²³ atoms

                            4.64 g of gold ----------  x

                            x = (4.64 x 6.023 x 10²³) / 197

                           x = 1.42 x 10²² atoms

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                x                        -------------------  4.12 x 10 ²⁴ molecules

                x = (4.12 x 10²⁴ x 180) / 6.023 x 10²³

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The correct option is; True.

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