<u>Answer:</u> The units used to express average kinetic energy of a substance is Joules.
<u>Explanation:</u>
Average kinetic energy is defined as the average of the kinetic energies of all the particles present in a system.
To calculate the average kinetic energy of the atom, we use the equation:

where,
K = average kinetic energy
k = Boltzmann constant = 
T = temperature (it is expressed in Kelvins)
So, the units of K will be:

Hence, the units used to express average kinetic energy of a substance is Joules.