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2 years ago

11

Using the thermodynamic information in the ALEKS Data tab, calculate the boiling point of titanium tetrachloride . Round your an

swer to the nearest degree.

1 answer:

ddd [48]2 years ago

5 0

Answer:

The boiling point is 308.27 K (35.27°C)

Explanation:

The chemical reaction for the boiling of titanium tetrachloride is shown below:

Ti $Cl_{4(l)}$ ⇒ Ti $Cl_{4(g)}$

ΔH° $_{f}$ (Ti $Cl_{4(l)}$ ) = -804.2 kJ/mol

ΔH° $_{f}$ (Ti $Cl_{4(g)}$ ) = -763.2 kJ/mol

Therefore,

ΔH° $_{f}$ = ΔH° $_{f}$ (Ti $Cl_{4(g)}$ ) - ΔH° $_{f}$ (Ti $Cl_{4(l)}$ ) = -763.2 - (-804.2) = 41 kJ/mol = 41000 J/mol

Similarly,

s°(Ti $Cl_{4(l)}$ ) = 221.9 J/(mol*K)

s°(Ti $Cl_{4(g)}$ ) = 354.9 J/(mol*K)

Therefore,

s° = s° (Ti $Cl_{4(g)}$ ) - s°(Ti $Cl_{4(l)}$ ) = 354.9 - 221.9 = 133 J/(mol*K)

Thus, T = ΔH° $_{f}$ /s° = [41000 J/mol]/[133 J/(mol*K)] = 308. 27 K or 35.27°C

Therefore, the boiling point of titanium tetrachloride is 308.27 K or 35.27°C.

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A frictionless piston cylinder device is subjected to 1.013 bar external pressure. The piston mass is 200 kg, it has an area of

Bad White [126]

Answer:

a) $T_{2} = 360.955\,K$ , $P_{2} = 138569.171\,Pa\,(1.386\,bar)$ , b) $T_{2} = 347.348\,K$ , $V_{2} = 0.14\,m^{3}$

Explanation:

a) The ideal gas is experimenting an isocoric process and the following relationship is used:

$\frac{T_{1}}{P_{1}} = \frac{T_{2}}{P_{2}}$

Final temperature is cleared from this expression:

$Q = n\cdot \bar c_{v}\cdot (T_{2}-T_{1})$

$T_{2} = T_{1} + \frac{Q}{n\cdot \bar c_{v}}$

The number of moles of the ideal gas is:

$n = \frac{P_{1}\cdot V_{1}}{R_{u}\cdot T_{1}}$

$n = \frac{\left(101,325\,Pa + \frac{(200\,kg)\cdot (9.807\,\frac{m}{s^{2}} )}{0.15\,m^{2}} \right)\cdot (0.12\,m^{3})}{(8.314\,\frac{Pa\cdot m^{3}}{mol\cdot K} )\cdot (298\,K)}$

$n = 5.541\,mol$

The final temperature is:

$T_{2} = 298\,K +\frac{10,500\,J}{(5.541\,mol)\cdot (30.1\,\frac{J}{mol\cdot K} )}$

$T_{2} = 360.955\,K$

The final pressure is:

$P_{2} = \frac{T_{2}}{T_{1}}\cdot P_{1}$

$P_{2} = \frac{360.955\,K}{298\,K}\cdot \left(101,325\,Pa + \frac{(200\,kg)\cdot (9.807\,\frac{m}{s^{2}} )}{0.15\,m^{2}}\right)$

$P_{2} = 138569.171\,Pa\,(1.386\,bar)$

b) The ideal gas is experimenting an isobaric process and the following relationship is used:

$\frac{T_{1}}{V_{1}} = \frac{T_{2}}{V_{2}}$

Final temperature is cleared from this expression:

$Q = n\cdot \bar c_{p}\cdot (T_{2}-T_{1})$

$T_{2} = T_{1} + \frac{Q}{n\cdot \bar c_{p}}$

$T_{2} = 298\,K +\frac{10,500\,J}{(5.541\,mol)\cdot (38.4\,\frac{J}{mol\cdot K} )}$

$T_{2} = 347.348\,K$

The final volume is:

$V_{2} = \frac{T_{2}}{T_{1}}\cdot V_{1}$

$V_{2} = \frac{347.348\,K}{298\,K}\cdot (0.12\,m^{3})$

$V_{2} = 0.14\,m^{3}$

4 0

3 years ago

A certain compound was found to have the molecular formula C5H12O2. To which of the following compound classes could the compoun

IgorC [24]

Answer : The given compound belongs to ether and alcohol.

Explanation :

The chemical formula of the given compound is, $C_5H_{12}O_2$

First we have to calculate the degree of unsaturation.

Formula used:

Degree of unsaturation = $\frac{2C+2+N-X-H}{2}$

where,

C = number of carbon

H = number of hydrogen

N = number of nitrogen

X = number of halogen

Degree of unsaturation = $\frac{2\times 5+2+0-0-12}{2}=0$

The degree of unsaturation is, 0 that means there is no double or triple bond in the compound only single bond is present between the atoms.

Thus, the given compound belongs to ether and alcohol.

6 0

2 years ago

Name the bond between atoms that share electrons

Masteriza [31]

Answer:

1) Covalent bond, in chemistry, the interatomic linkage that results from the sharing of an electron pair between two atoms. The binding arises from the electrostatic attraction of their nuclei for the same electrons.

2)A molecule is the smallest particle in a chemical element or compound that has the chemical properties of that element or compound. Molecules are made up of atoms that are held together by chemical bonds. These bonds form as a result of the sharing or exchange of electrons among atoms.

3)Hydrogen (H2), oxygen (O2), and chlorine (Cl2) molecules, for example, each contains two atoms. Another form of oxygen, ozone (O3), has three atoms, and sulfur (S8) has eight atoms. All elemental molecules are made of atoms of a single element.

Explanation:

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8 0

2 years ago

A sample of gas initially has a volume of 2.25 L at 350 K and a pressure of 1.75 atm. What will be sample pressure if the volume

IRINA_888 [86]

Answer:

8.44 atm

Explanation:

From the question given above, the following data were obtained:

Initial volume (V₁) = 2.25 L

Initial temperature (T₁) = 350 K

Initial pressure (P₁) = 1.75 atm

Final volume (V₂) = 1 L

Final temperature (T₂) = 750 K

Final pressure (P₂) =?

The final pressure of the gas can be obtained as illustrated below:

P₁V₁/T₁ = P₂V₂/T₂

1.75 × 2.25 / 350 = P₂ × 1 / 750

3.9375 / 350 = P₂ / 750

Cross multiply

350 × P₂ = 3.9375 × 750

350 × P₂ = 2953.125

Divide both side by 350

P₂ = 2953.125 / 350

P₂ = 8.44 atm

Thus, the final pressure of the gas is 8.44 atm.

7 0

2 years ago

How many atoms are 0.750 moles of zinc?

Darya [45]

<span>.750 moles X (6.02 x10^23 atoms/1 mol)= 4.52 X 10^23 atoms is the answer </span>

7 0

3 years ago