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Alex73 [517]
3 years ago
11

Using the thermodynamic information in the ALEKS Data tab, calculate the boiling point of titanium tetrachloride . Round your an

swer to the nearest degree.
Chemistry
1 answer:
ddd [48]3 years ago
5 0

Answer:

The boiling point is 308.27 K (35.27°C)

Explanation:

The chemical reaction for the boiling of titanium tetrachloride is shown below:

TiCl_{4(l)} ⇒ TiCl_{4(g)}

ΔH°_{f} (TiCl_{4(l)}) = -804.2 kJ/mol

ΔH°_{f} (TiCl_{4(g)}) = -763.2 kJ/mol

Therefore,

ΔH°_{f} = ΔH°_{f} (TiCl_{4(g)}) - ΔH°_{f} (TiCl_{4(l)}) = -763.2 - (-804.2) = 41 kJ/mol = 41000 J/mol

Similarly,

s°(TiCl_{4(l)}) = 221.9 J/(mol*K)

s°(TiCl_{4(g)}) = 354.9 J/(mol*K)

Therefore,

s° = s° (TiCl_{4(g)}) - s°(TiCl_{4(l)}) = 354.9 - 221.9 = 133 J/(mol*K)

Thus, T = ΔH°_{f} /s° = [41000 J/mol]/[133 J/(mol*K)] = 308. 27 K or 35.27°C

Therefore, the boiling point of titanium tetrachloride is 308.27 K or 35.27°C.

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