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notsponge [240]

3 years ago

6

We know that for a given reaction when the temperature increases from 100 k to 200 k the rate constant doubles. What is the acti

vation energy in kj/mol

1 answer:

Alenkasestr [34]3 years ago

5 0

Answer:

The activation energy of the reaction is 1.152 kJ/mol.

Explanation:

Activation energy is the minimum amount which is absorbed by the reactant molecules to undergo chemical reaction.

Initial temperature of reaction = $T_1=100 K$

Final temperature of reaction = $T_2=200 K$

Initial rate of the reaction at 100 k = $K_1=k$

Final rate of the reaction at 200 k = $K_2=2k$

Activation energy is calculated from the formula:

$\log\frac{K_2}{K_1}=\frac{E_a}{2.303\times R}(\frac{T_2-T_1}{T_1T_2})$

R = Universal gas constant = 8.314 J/ K mol

$\log\frac{2k}{k}=\frac{E_a}{2.303\times 8.314 J/K mol}(\frac{200 K-100K}{200 K\times 100K})$

$E_a=1,152.772 J/mol=1.152 kJ/mol$

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Toluene (C6H5CH3 ), an organic compound often used as a solvent in paints, is mixed with a similar organic compound, benzene (C6

Sergeeva-Olga [200]

Explanation:

The given data is as follows.

Weight of solute = 75.8 g, Molecular weight of solute (toulene) = 92.13 g/mol, volume = 200 ml

Therefore, molarity of toulene is calculated as follows.

Molarity = $\frac{\text{weight of solute}}{\text{molecular weight of solute}} \times \frac{1000}{\text{volume of solution in ml}}$

= $\frac{75.8 g}{92.13 g/mol} \times \frac{1000}{200 ml}$

= 4.11 M

Hence, molarity of toulene is 4.11 M.

As molality is the number of moles of solute present in kg of solvent.

So, we will calculate the molality of toulene as follows.

Molality = $\frac{\text{given weight of solute}}{\text{given molecular weight of solute}} \times \frac{1000}{\text{weight of solvent in grams}}$

= $\frac{75.8 g}{92.13 g/mol} \times \frac{1000}{95.6 g}$

= 8.6 m

Hence, molality of given toulene solution is 8.6 m.

Now, calculate the number of moles of toulene as follows.

No. of moles = $\frac{mass}{\text{molar mass}}$

= $\frac{75.8 g}{92.13 g/mol}$

= 0.8227 mol

Now, no. of moles of benzene will be as follows.

No. of moles = $\frac{mass}{\text{molar mass}}$

= $\frac{95.6 g}{78.11 g/mol}$

= 1.2239 mol

Hence, the mole fraction of toulene is as follows.

Mole fraction = $\frac{\text{moles of toulene}}{\text{total moles}}$

= $\frac{0.8227 mol}{(0.8227 + 1.2239) mol}$

= 0.402

Hence, mole fraction of toulene is 0.402.

As density of given solution is 0.857 $g/cm^{3}$ so, we will calculate the mass of solution as follows.

Density = $\frac{mass}{volume}$

0.857 $g/cm^{3}$ = $\frac{mass}{200 ml}$ (As 1 $cm^{3}$ = 1 g)

mass = 171.4 g

Therefore, calculate the mass percent of toulene as follows.

Mass % = $\frac{\text{mass of solute}}{\text{mass of solution}} \times 100$

= $\frac{75.8 g}{171.4 g} \times 100$

= 44.22%

Therefore, mass percent of toulene is 44.22%.

8 0

3 years ago

the speed limit is posted as 35 km/hr . your speedometer reads that you are going 40 miles/hr. are you speeding?

Morgarella [4.7K]

No, because 40 miles is the same as nearly 25 km/h.

4 0

3 years ago

Calculate the average reaction rate expressed in moles h2 consumed per liter per second

djyliett [7]

Answer:

Average rate of reaction expressed in moles H₂ consumed per liter per second = 0.0025 M/s = 0.0025 mol/L.s

Explanation:

The complete, correct Question, is presented in the attached image to this answer.

The average rate of reaction in terms of the reactant is defined as the total amount of reactant consumed over a period of time divided by total period of time.

Mathematically,

Average rate of reaction = (change in concentration of H₂ over a period of time) ÷ (total period of time)

Average rate of reaction = (-ΔC)/(Δt)

The minus sign is there because the concentration of reactants reduce with time.

change in concentration of H₂ = -ΔC

= -(0.02 - 0.03) = 0.01 M

Time = Δt = 4 - 0 = 4.0 s

Average rate of reaction = (0.01/4) = 0.0025 M/s

We could solve for the average rate of reaction expressed in moles Cl₂ consumed per liter per second

change in concentration of Cl₂ = -ΔC

= -(0.04 - 0.05) = 0.01 M

Time = Δt = 4 - 0 = 4.0 s

Average rate of reaction = (0.01/4) = 0.0025 M/s = 0.0025 mol/L.s

Hope this Helps!!!

8 0

3 years ago

The solubility of water in diethyl ether has been reported to be 1.468 % by mass.' Assuming that 23.0 mL of diethyl ether were a

melomori [17]

Explanation:

As it is given that solubility of water in diethyl ether is 1.468 %. This means that in 100 ml saturated solution water present is 1.468 ml.

Hence, amount of diethyl ether present will be calculated as follows.

(100ml - 1.468 ml)

= 98.532 ml

So, it means that 98.532 ml of diethyl ether can dissolve 1.468 ml of water.

Hence, 23 ml of diethyl ether can dissolve the amount of water will be calculated as follows.

Amount of water = $\frac{1.468 ml \times 23 ml}{98.532 ml}$

= 0.3427 ml

Now, when magnesium dissolves in water then the reaction will be as follows.

$Mg + H_{2}O \rightarrow Mg(OH)_{2}$

Molar mass of Mg = 24.305 g

Molar mass of $H_{2}O$ = 18 g

Therefore, amount of magnesium present in 0.3427 ml of water is calculated as follows.

Amount of Mg = $\frac{24.305 g \times 0.3427 ml}{18 g}$

= 0.462 g

6 0

3 years ago

Which atom in the ground state has the same electron configuration as a calcium ion, Ca2+, in the ground state?(1) Ar(2) K(3) Mg

Irina-Kira [14]

atoms are made of 3 types of subatomic particles; electrons, protons and neutrons

atomic number is the number of protons. atomic number is characteristic for the element. In ground state atoms, the number of electrons and protons are the same.

the electronic configuration of Ca in the ground state is

Ca - 1s² 2s² 2p⁶ 3s² 3p⁶ 4s²

when Ca loses its 2 valence electrons, it becomes positively charged and the electronic configuration becomes

Ca - 1s² 2s² 2p⁶ 3s² 3p⁶

number of electrons in Ca²⁺ is 18

the atom in the ground state would have the same number of electrons and protons. Therefore number of protons are 18. then the atomic number of the element is 18

the atom having an atomic number of 18 is Ar.

the answer is 1) Ar

7 0

3 years ago

Read 2 more answers