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3 years ago

If a 0.2g of oil consumed 1ml of sodium thiosulphate, calculate its iodine value and classify the oil?

1 answer:

6 0

Iodine value is a measure of the degree of unsaturation in fats and oils. It is essentially the number of grams of iodine consumed by 100 g of fat. If the iodine number is in the range of 0-70 then it is a fat, any value above 70 is considered an oil.

Formula:

Iodine number = (ml of 0.1 N Thiosulphate blank- ml of 0.1N thiosulphate test) * 12.7 *100/1000* wt of sample

vol of thiosulphate required to titrate test sample (given oil) = 1 ml

wt of sample = 0.2 g

Information on the volume of thiosulphate required to titrate the blank solution is essential for calculation.

Iodine number = (X-1.0) * 12.7 * 100/1000* 0.2 = (X-1.0)*6.35

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3 years ago

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While ethanol is produced naturally by fermentation, e.g. in beer- and wine-making, industrially it is synthesized by reacting e

sp2606 [1]

The question is incomplete, here is the complete question:

While ethanol is produced naturally by fermentation, e.g. in beer- and wine-making, industrially it is synthesized by reacting ethylene with water vapor at elevated temperatures.

A chemical engineer studying this reaction fills a 1.5 L flask at 12°C with 1.8 atm of ethylene gas and 4.7 atm of water vapor. When the mixture has come to equilibrium she determines that it contains 1.16 atm of ethylene gas and 4.06 atm of water vapor.

The engineer then adds another 1.2 atm of ethylene, and allows the mixture to come to equilibrium again. Calculate the pressure of ethanol after equilibrium is reached the second time. Round your answer to 2 significant digits.

Answer: The partial pressure of ethanol after equilibrium is reached the second time is 1.0 atm

Explanation:

We are given:

Initial partial pressure of ethylene gas = 1.8 atm

Initial partial pressure of water vapor = 4.7 atm

Equilibrium partial pressure of ethylene gas = 1.16 atm

Equilibrium partial pressure of water vapor = 4.06 atm

The chemical equation for the reaction of ethylene gas and water vapor follows:

$CH_2CH_2(g)+H_2O(g)\rightleftharpoons CH_3CH_2OH(g)$

Initial: 1.8 4.7

At eqllm: 1.8-x 4.7-x

Evaluating the value of 'x'

$\Rightarrow (1.8-x)=1.16\\\\x=0.64$

The expression of $K_p$ for above equation follows:

$K_p=\frac{p_{CH_3CH_2OH}}{p_{CH_2CH_2}\times p_{H_2O}}$

$p_{CH_2CH_2}=1.16atm\\p_{H_2O}=4.06atm\\p_{CH_3CH_2OH}=0.64atm$

Putting values in above expression, we get:

$K_p=\frac{0.64}{1.16\times 4.06}\\\\K_p=0.136$

When more ethylene is added, the equilibrium gets re-established.

Partial pressure of ethylene added = 1.2 atm

$CH_2CH_2(g)+H_2O(g)\rightleftharpoons CH_3CH_2OH(g)$

Initial: 2.36 4.06 0.64

At eqllm: 2.36-x 4.06-x 0.64+x

Putting value in the equilibrium constant expression, we get:

$0.136=\frac{(0.64+x)}{(2.36-x)\times (4.06-x)}\\\\x=0.363,13.41$

Neglecting the value of x = 13.41 because equilibrium partial pressure of ethylene and water vapor will become negative, which is not possible.

So, equilibrium partial pressure of ethanol = (0.64 + x) = (0.64 + 0.363) = 1.003 atm

Hence, the partial pressure of ethanol after equilibrium is reached the second time is 1.0 atm

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3 years ago

how many moles of a nonvolatile, nonelectrolyte solute are required to lower the freezing point of 1000 grams of water by 5.58

Ivan

Answer:

Explanation:

Using freezing point depression formula,

ΔTemp.f = Kf * b * i

Where,

ΔTemp.f = temp.f(pure solvent) - temp.f(solution)

b = molality

i = van't Hoff factor

Kf = cryoscopic constant

= 1.86°C/m for water

= (0 - (-5.58))/1.86

= 3.00 mol/kg

Assume 1 kg of water(solvent)

= (3.00 x 1)

= 3.00 mol.

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3 years ago