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3 years ago

If a 0.2g of oil consumed 1ml of sodium thiosulphate, calculate its iodine value and classify the oil?

1 answer:

6 0

Iodine value is a measure of the degree of unsaturation in fats and oils. It is essentially the number of grams of iodine consumed by 100 g of fat. If the iodine number is in the range of 0-70 then it is a fat, any value above 70 is considered an oil.

Formula:

Iodine number = (ml of 0.1 N Thiosulphate blank- ml of 0.1N thiosulphate test) * 12.7 *100/1000* wt of sample

vol of thiosulphate required to titrate test sample (given oil) = 1 ml

wt of sample = 0.2 g

Information on the volume of thiosulphate required to titrate the blank solution is essential for calculation.

Iodine number = (X-1.0) * 12.7 * 100/1000* 0.2 = (X-1.0)*6.35

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Ascorbic acid (H2C6H6O6; H2Asc for this problem), known as vitamin C, is a diprotic acid (Ka1= 1.0x10–5 and Ka2= 5x10–12) found

Igoryamba

Answer:

The concentrations are :

$[HAsc^-]=0.000702 M$

$[Asc^{2-}]=5.92\times 10^{-8} M$

The pH of the solution is 3.15.

Explanation:

$H_2Asc\rightleftharpoons HAs^-+H^+$ $K_{a1}=1.0\times 10^{-5}$

Initial

c 0 0

Equilibrium

c-x x x

$K_{a1}=\frac{[HAs^-][H^+]}{[H_2Asc]}$

$1.0\times 10^{-5}=\frac{x\times x}{(c-x)}$

$1.0\times 10^{-5}=\frac{x^2}{(0.050-x)}$

Solving for x:

x = 0.000702 M

$[HAsc^-]=0.000702 M$

$HAsc^-\rightleftharpoons As^{2-}+H^+$ $K_{a2}=5\times 10^{-12}$

Initially

x 0 0

At equilibrium ;

(x - y) y y

$K_{a2}=\frac{[As^{2-}][H^+]}{[HAsc^-]}$

$5\times 10^{-12}=\frac{y\times y}{(x-y)}$

$5\times 10^{-12}=\frac{y^2}{(x-y)}$

Putting value of x = 0.000702 M

$5\times 10^{-12}=\frac{y^2}{(0.000702 -y)}$

$y=5.92\times 10^{-8} M$

$[Asc^{2-}]=5.92\times 10^{-8} M$

Total concentration of $[H^+]=x+y=0.000702 M+5.92\times 10^{-8} M=7.0206\times 10^{-4} M$

The pH of the solution :

$pH=-\log[H^+]$

$pH=-\log[7.0206\times 10^{-4} M}=3.15$

7 0

3 years ago

Which acide will have more strength<br>out of two acids of pH<br>value 2<br>and 5 why<br>

gladu [14]

Ph 2 will ahve more strength due to the fact that its more acidic compared to pH 5.

the lower the number of a pH, the more it is heading towards being acidic, but the higher the number, the more it heads towards being an alkali. here is a ppt i made along time ago. hope it can help you . have a nice day

Download pptx

5 0

3 years ago

what would you be most likely to measure by immsering and object in water and seeing how much the water level rises

Katena32 [7]

Mass, if you know what element you are working with.

4 0

3 years ago

Green plants absorbs sunlight to power photosynthesis, the chemical synthesis of food from water and carbon dioxide. The compoun

Serggg [28]

Answer: The frequency of this light is $6.62\times 10^{14}s^{-1}$

Explanation:

To calculate the wavelength of light, we use the equation:

$\lambda=\frac{c}{\nu}$

where,

$\lambda$ = wavelength of the light = $453nm=453\times 10^{-9}m$

c = speed of light = $3.0\times 10^8m/s$

$\nu$ = frequency of light = ?

$\nu=\frac{3.0\times 10^8m/s}{453\times 10^{-9}m}=6.62\times 10^{14}s^{-1}$

The frequency of this light is $6.62\times 10^{14}s^{-1}$

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3 years ago

WHAT IS THE PERCENT BY VOLUME OF ETHANOL IN A SOLUTION THAT CONTAINS 35 mL ETHANOL IN 115 mL OF WATER?

Dmitry [639]

We need to first add both of the solution volumes together 35+115=150. Now we can divide the volume of the ethanol by the total volume 35/150=.233. To double check we can multiply the total volume by the percentage of ethanol by volume we got as a solution 150x.233=35. So the percentage by volume of ethanol in the solution is .233x100=23.3%.

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3 years ago