Answer:
neq N2O4 = 0.9795 mol.....P = 0.5 atm; T = 25°C
Explanation:
ni change eq.
N2O4 1 1 - x 0.8154.....P = 1 atm; T = 25°C
NO2 0 0 + x x
∴ x = neq = Peq.V / R.T.....ideal gas mix
if P = 0.5 atm, T = 25°C; assuming: V = 1 L
⇒ x = neq = ((0.5 atm)(1 L))/((0.082 atm.L/K.mol)(298 K))
⇒ x = neq = 0.0205 mol
⇒ neq N2O4 = 1 - x = 1 - 0.0205 = 0.9795 mol
The question is incomplete.
You need two additional data:
1) the original volume
2) what solution you added to change the volume.
This is a molarity problem, so remember molarity definition and formula:
M = n / V in liters: number of moles per liter of solution
To give you the key to answer this kind of questions, supppose the original volumen was 1 ml and that you added only water (solvent).
The original solution was:
V= 1 ml
M = 0.2 M
Using the formula for molarity, M = n / V
n = M×V = 0.2 M × (1 / 10000)l = 0.0002 moles
For the final solution:
n = 0.0002 moles
M = 0.04
From M = n / V ⇒ V = n / M = 0.002 moles / 0.04 M = 0.05 l
Change to ml ⇒ 0.05 l × 1000 ml / l = 50 ml. This would be the answer for the hypothetical problem that I assumed for you.
I hope this gives you all the cues you need to answer similar problems about molarity.
