Answer:
131.5 kJ
Explanation:
Let's consider the following reaction.
CaCO₃(s) → CaO(s) + CO₂(g)
First, we will calculate the standard enthalpy of the reaction (ΔH°).
ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g)
) - 1 mol × ΔH°f(CaCO₃(s)
)
ΔH° = 1 mol × (-634.9 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1207.6 kJ/mol)
ΔH° = 179.2 kJ
Then, we calculate the standard entropy of the reaction (ΔS°).
ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g)
) - 1 mol × S°(CaCO₃(s)
)
ΔS° = 1 mol × (38.1 J/mol.K) + 1 mol × (213.8 J/mol.K) - 1 mol × (91.7 J/mol.K)
ΔS° = 160.2 J/K = 0.1602 kJ/K
Finally, we calculate the standard Gibbs free energy of the reaction at T = 25°C = 298 K.
ΔG° = ΔH° - T × ΔS°
ΔG° = 179.2 kJ - 298 K × 0.1602 kJ/K
ΔG° = 131.5 kJ
Answer:
D. The electron-withdrawing fluorine atoms pull electron density from the oxygen in trifluoroacetate. The negative charge is more stabilized in trifluoroacetate by this effect.
Explanation:
The structures of trifluoroacetate and acetic acid are both shown in the image attached.
The trifluoroacetate anion (CF3CO2-), just like the acetate anion has in the middle, two oxygen atoms.
However, in the trifluoroacetate anion, there are also three electronegative fluorine atoms attached to the nearby carbon atom attached to the carbonyl, and these pull some electron density through the sigma bonding network away from the oxygen atoms, thereby spreading out the negative charge further. This effect, called the "inductive effect" stabilizes the anion formed,the trifouoroacetate anion is thus more stabilized than the acetate anion.
Hence, trifluoroacetic acid is a stronger acid than acetic acid, having a pKa of -0.18.
The pH of the diluted HCl solution is 1.3.
Explanation:
Given:
The concentrated HCl solution of 8.0 M. The 1.5 mL of 8.0 M HCl is diluted with water to 250 mL volume.
To find:
The pH of the diluted HCl solution.
Solution
- The concentration of the HCl solution before dilution =

- The volume of the HCl solution taken for dilution =

- The concentration of the HCl solution after dilution =

- The volume of the HCl solution after dilution =

Using the Dilution equation:

The concentration of diluted HCl solution = 0.048 M

In the 1 M solution of HCl, there are 1 M of hydrogen ion, then the concentration of hydrogen ions in 0.048 M of HCl will be:
![[H^+]=1\times 0.048M=0.048 M](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3D1%5Ctimes%200.048M%3D0.048%20M)
The pH of the diluted HCl solution :
![pH=-\log [H^+]\\=-\log [0.048M]=1.18 \approx 1.3](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH%5E%2B%5D%5C%5C%3D-%5Clog%20%5B0.048M%5D%3D1.18%20%5Capprox%201.3)
The pH of the diluted HCl solution is 1.3.
Learn more about the dilution equation here:
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A sodium ion has a charge of +1
A chlorine ion has a charge of -1
These ions are bonded by electrostatic forces, by the principles rule that all opposites attract. So it looks like a one Na atom bonded to one Cl atom. Like a double scoop ice cream that's not stacked