Answer:
Initial concentration of HI is 5 mol/L.
The concentration of HI after 
is 0.00345 mol/L.
Explanation:
Rate Law: ![k[HI]^2 ](https://tex.z-dn.net/?f=k%5BHI%5D%5E2%0A)
Rate constant of the reaction = k = 
Order of the reaction = 2
Initial rate of reaction = 
Initial concentration of HI =![[A_o]](https://tex.z-dn.net/?f=%5BA_o%5D)
![1.6\times 10^{-7} mol/L s=(6.4\times 10^{-9} L/mol s)[HI]^2](https://tex.z-dn.net/?f=1.6%5Ctimes%2010%5E%7B-7%7D%20mol%2FL%20s%3D%286.4%5Ctimes%2010%5E%7B-9%7D%20L%2Fmol%20s%29%5BHI%5D%5E2)
![[A_o]=5 mol/L](https://tex.z-dn.net/?f=%5BA_o%5D%3D5%20mol%2FL)
Final concentration of HI after t = [A]
t =
Integrated rate law for second order kinetics is given by:
![\frac{1}{[A]}=kt+\frac{1}{[A_o]}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%3Dkt%2B%5Cfrac%7B1%7D%7B%5BA_o%5D%7D)
![\frac{1}{[A]}=6.4\times 10^{-9} L/mol s\times 4.53\times 10^{10} s+\frac{1}{[5 mol/L]}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%3D6.4%5Ctimes%2010%5E%7B-9%7D%20L%2Fmol%20s%5Ctimes%204.53%5Ctimes%2010%5E%7B10%7D%20s%2B%5Cfrac%7B1%7D%7B%5B5%20mol%2FL%5D%7D)
![[A]=0.00345 mol/L](https://tex.z-dn.net/?f=%5BA%5D%3D0.00345%20mol%2FL)
The concentration of HI after is 0.00345 mol/L.
Answer:
25°C
Explanation:
Combined Gas Law (P₁V₁)/T₁ = (P₂V₂)/T₂
(0.947 atm)(150 mL)/25°C = (0.987 atm)(144mL)/T₂
5.682 = 142.128/T₂
T₂ = 142.128/5.682
T₂ = 25.0137272756°C = 25°C
<span>There are only three stereoisomers of 1,2-dimethylcyclopentane. As there are only two chiral carbons, so the maximum number of stereoisomers is 4, but two are the same meso-compound which means that there are only 3.</span>
Answer:
Option b, The change in free energy of the reaction (ΔG)
Explanation:
Gibbs free energy is a measure of amount of usable energy in the system.
It is related with enthalpy (H), entropy (S) and temprature (T) as:
G = H - TS
The Gibbs free energy change (ΔG) provide spontaneity of a chemical reaction.
If ΔG is negative, then reaction is spontaneous that means reaction is moving towards forward direction.
If ΔG is positive, then reaction is non-spontaneous that means reaction is moving in backward direction.
If ΔG is zero, then reaction is at equilibrium.
Change in enthalpy only gives informtion about heat involed in a chemical reaction, it does not give information about direction of the reaction.
So, among the given options, option b is correct.
