Sucrose, a sweet, white crystalline substance, C12 H22 O11, OBTAINED CHIEFLY FROM THE JUICE OF THE SUGAR CANE AND SUGAR BEET, BUT ALSO PRESENT IN SORGHUM, THE sugar maple, some palms, and various other plants, and having extensive nutritional, pharmaceutical, and industrial uses; any of the class of carbohydrates to which this substance belongs, as glucose, levulose, and lactose.
Answer:
[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.
Explanation:
Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.
Analysis:
H₂CO₃(aq) ⇄ H⁺(aq) + HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷
C(i) 0.115M 0 0
ΔC -x +x +x
C(eq) 0.115M - x x x
≅ 0.115M
Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M
= 4.3 x 10⁻⁷ => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.
In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion concentration, the hydroxide ion concentration is then calculated from
[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.
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NOTE: The 2.32 x 10⁻⁴M value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.
Answer: Here's the answer hope this helps
Explanation: