The absorbance reported by the defective instrument was 0.3933.
Absorbance A = - log₁₀ T
Tm = transmittance measured by spectrophotometer
Tm = 0.44
Absorbance reported in this equipment = -log₁₀ (0.44) = 0.35654
True absorbance can be calculated by true transmittance, Tm = T+S(α-T)
S = fraction of stray light = 6%= 6/100 = 0.06
α= 1, ideal case
T = true transmittance of the sample
Tm = T+S(α-T)
now, T= Tm-S/ 1-S = 0.44-0.06/ 1-0.06 = 0.404233
therefore, actual reading measured is A = -log₁₀ T = -log₁₀ (0.404233)
i.e; 0.3933
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Carbon -13 has 7 neutrons and carbon -12 has six neutrons. Carbon -12 is the most common isotope of Carbon. Carbon -14 is radioactive and vary rare. The symbols for the isotopes of Carbon atoms shown here indicate they each have six protons but mass numbers of 14, 13, and 12. Hope this helps. :)
Answer to this is Radioactive isotopes.
Isotopes are the species of the same element having different atomic masses that means the number of protons remains the same but number of neutrons do differ. For example
and
are the two isotopes of Hydrogen (
).
Radioactive isotopes are the isotopes which release some kind of energy in the form of alpha particles, beta particles or gamma radiation. Examples of each of the decay processes are :
Alpha Decay: In this decay one alpha particle having atomic mass 4 and atomic number 2 or we can say a He molecule will come out. 
Beta Decay: In this decay a
particle is emitted increasing the atomic number of the reactant by 1 unit.

Gamma Radiation: In this type of reaction only radiation is emitted out which does not change the original molecule.

Solving part-1 only
#1
KMnO_4
- Transition metal is Manganese (Mn)
#2
Actually it's the oxidation number of Mn
Let's find how?




- x is the oxidation number
#3
- Purple as per the color of potassium permanganate
#4
