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Triss [41]
3 years ago
9

Driving cars lowers the pH of the oceans by _______.

Chemistry
2 answers:
Naddika [18.5K]3 years ago
6 0
A) releasing CO2 that dissolves and forms acid in the oceans (i think i'm sorry if its wrong)
balu736 [363]3 years ago
5 0

Answer: Option (a) is the correct answer.

Explanation:

When CO_{2} is released from driving cars, some of which is absorbed by the plants but the rest of CO_{2} reacts with the sea or ocean water.

It reacts with water molecules and changes the chemistry of ocean water by lowering its pH. As it is known that when pH becomes lower then the substance becomes acidic in nature.

Thus, we can conclude that driving cars lowers the pH of the oceans by releasing CO_{2} that dissolves and forms acid in the oceans.

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pH = 13.5

Explanation:

Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:

\text{HAc} + \text{OH}^{-} \to \text{Ac}^{-} + \text{H}_2\text{O}

The mixture would contain

  • 0.4 \times 0.5 - 0.1 \times 0.5 = 0.15 \; \text{mol} of \text{OH}^{-} and
  • 0.1 \times 0.5 = 0.05 \; \text{mol} of \text{Ac}^{-}

if \text{Ac}^{-} undergoes no hydrolysis; the solution is of volume 0.1 + 0.4 = 0.5 \; \text{L} after the mixing. The two species would thus be of concentration 0.30 \; \text{mol} \cdot \text{L}^{-1} and 0.10 \; \text{mol} \cdot \text{L}^{-1}, respectively.

Construct a RICE table for the hydrolysis of \text{Ac}^{-} under a basic aqueous environment (with a negligible hydronium concentration.)

\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}

The question supplied the <em>acid</em> dissociation constant pK_afor acetic acid \text{HAc}; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant pK_b for its conjugate base, \text{Ac}^{-}. The following relationship relates the two quantities:

pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})

... where the water self-ionization constant pK_w \approx 14 under standard conditions. Thus pK_{b} (\text{Ac}^{-}) = 14 - 4.7 = 9.3. By the definition of pK_b:

[\text{HAc} (aq)] \cdot [\text{OH}^{-} (aq)] / [\text{Ac}^{-} (aq) ] = K_b =  10^{-pK_{b}}

x \cdot (0.3 + x) / (0.1 - x) = 10^{-9.3}

x = 1.67 \times 10^{-10} \; \text{M} \approx 0 \; \text{M}

[\text{OH}^{-}] = 0.30 +x \approx 0.30 \; \text{M}

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