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galina1969 [7]
3 years ago
11

Assume the weight of an average adult is 70. kg, and that 420. kJ of heat are evolved per mole of oxygen consumed as a result of

the oxidation of foodstuffs, knowing that the number of moles of O2 inhaled per minutes are 0.02 mol/min. Suppose an adult body were encased in a thermally insulating barrier. If as a result of this barrier all the heat evolved by metabolism of foodstuffs were retained by the body, what would the temperature difference of the body reach after 3 hours
Chemistry
1 answer:
seraphim [82]3 years ago
6 0

Answer:

The temperature difference of the body after 3 hours = 5.16 K

Explanation:

we know that the number of moles of O₂ inhaled are 0.02 mole/min⁻¹

                                   or, 1.2 mole.h⁻¹

The average heat evolved by the oxidation of foodstuffs is then:

⇒          Q avg =\frac{1.2 X 420 X 10^{3} }{70} = 7.2 kj.h⁻¹.Kg⁻¹

the heat produced after 3 h would be:

                 =    7.2 kj. h⁻¹.Kg⁻¹ x 3 h

                 = 21.6 kj. kg⁻¹

                 = 21.6 x 10³ j kg⁻¹

We know Qp = Cp x ΔT

Assume the heat capacity of the body is 4.18 J g⁻¹K⁻¹

⇒ ΔT = \frac{Qp}{Cp}

⇒ ΔT = \frac{(21.6 X 10^{3} j.kg^{-1} ) }{(4.18 j k^{-1}g^{-1})   X (1000g.kg^{-1} )}

⇒ ΔT = 5.16 K

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jeyben [28]

Hey there!:

Molar mass of Mg(OH)2 = 58.33 g/mol


number of moles Mg(OH)2 :

moles of Mg(OH)2 = 30.6 / 58.33 =>  0.5246 moles

Molar mass of H3PO4 =  97.99 g/mol

number of moles H3PO4:

moles of Mg(OH)2 = 63.6 / 97.99 => 0.649 moles

Balanced chemical equation is:


3 Mg(OH)2 + 2 H3PO4 --->  Mg3(PO4)2 + 6 H2O


3 mol of Mg(OH)2 reacts with 2 mol of H3PO4  ,for 0.5246 moles of Mg(OH)2, 0.3498 moles of H3PO4 is required , but we have 0.649 moles of H3PO4, so, Mg(OH)2 is limiting reagent !

Now , we will use Mg(OH)2 in further calculation  .

Molar mass of Mg3(PO4)2 = 262.87 g/mol

According to balanced equation  :

mol of Mg3(PO4)2 formed = (1/3)* moles of Mg(OH)2


= (1/3)*0.5246


= 0.1749 moles of Mg3(PO4)2

use :

mass of Mg3(PO4)2 = number of mol * molar mass


= 0.1749 *  262.87

= 46 g of Mg3(PO4)2

Therefore:

% yield = actual mass * 100 / theoretical mass

% = 34.7 * 100 / 46

% = 3470 / 46

= 75.5%


Hope that helps!




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