Answer:
The pressure is 58.75 atm.
Explanation:
From Vanderwaal's equation,
P = nRT/(V-nb) - n^2a/V^2
n is the number of moles of SO2 = mass/MW = 500/64 = 7.81 mol
R is gas constant = 0.0821 L.atm/mol.K
T is temperature of the vessel = 633 K
V is volume of the vessel = 6.3 L
a & b are Vanderwaal's constant = 6.865 L^2.atm/mol^2 and 0.0567 L/mol respectively.
P = (7.81×0.0821×633)/(6.3 - 7.81×0.05679) - (7.81^2 × 6.865)/6.3^2 = 69.30 - 10.55 = 58.75 atm