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liubo4ka [24]
3 years ago
13

Muscle physiologists study the accumulation of lactic acid [ch3ch(oh)cooh] during exercise. food chemists study its occurrence i

n sour milk, beer, wine, and fruit. industrial microbiologists study its formation by various bacterial species from carbohydrates. a biochemist prepares a lactic acid-lactate buffer by mixing 225 ml of 0.85 m lactic acid (ka = 1.38 × 10−4) with 435 ml of 0.68 m sodium lactate. what is the buffer ph?
Chemistry
1 answer:
Drupady [299]3 years ago
7 0
The provided information are:
volume of 0.85 M lactic acid = 225 ml
volume of 0.68 M sodium lactate = 435 ml
Ka of the lactate buffer = 1.38 x 10⁻⁴
 The equation for dissociation of lactic acid is:
CH₃CH(OH)COOH(aq) + H₂O ⇄ CH₃CH(OH)COO⁻(aq) + H₃O⁺(aq)
The pH of buffer is calculated from Henderson-Hasselbalch equation, which is:
pH = pKa + log \frac{[conjugated base]}{[Acid]}
pKa = - log Ka = - log (1.38 x 10⁻⁴) = 3.86 
The number of moles of lactic acid and lactate are as follows:
n (Lactic acid) = 225 ml x 0.85 mmol/ml = 191.25 mmol
n (Lactate) = 435 ml x 0.68 mmol/ml = 295.8 mmol
The number of moles of lactic acid and lactate in total volume of the solution:
[CH₃CH(OH)COOH] = n (lactic acid) / 660 ml = 191.25 mmol / 660 ml = 0.29 M
[CH₃CH(OH)COO⁻] = n (lactate) / 660 ml = 0.45 M
pH = 3.86 + log \frac{0.45 M}{0.29 M} = 3.86 + 0.191 = 4.05
So the pH of given solution is 4.05
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A 3.452 g sample containing an unknown amount of a Ce(IV) salt is dissolved in 250.0-mL of 1 M H2SO4. A 25.00 mL aliquot is anal
SOVA2 [1]

Answer:

1,812 wt%

Explanation:

The reactions for this titration are:

2Ce⁴⁺ + 3I⁻ → 2Ce³⁺ + I₃⁻

I₃⁻ + 2S₂O₃⁻ → 3I⁻ + S₄O₆²⁻

The moles in the end point of S₂O₃⁻ are:

0,01302L×0,03428M Na₂S₂O₃ = 4,463x10⁻⁴ moles of S₂O₃⁻. As 2 moles of S₂O₃⁻ react with 1 mole of I₃⁻, the moles of I₃⁻ are:

4,463x10⁻⁴ moles of S₂O₃⁻×\frac{1molI_{3}^-}{2molS_{2}O_{3}^-} = 2,2315x10⁻⁴ moles of I₃⁻

As 2 moles of Ce⁴⁺ produce 1 mole of I₃⁻, the moles of Ce⁴⁺ are:

2,2315x10⁻⁴ moles of I₃⁻×\frac{2molCe^{4+}}{1molI_{3}^-} = 4,463x10⁻⁴ moles of Ce(IV). These moles are:

4,463x10⁻⁴ moles of Ce(IV)×\frac{140,116g}{1mol} = <em>0,0625 g of Ce(IV)</em>

As the sample has a 3,452g, the weight percent is:

0,0625g of Ce(IV) / 3,452g × 100 = <em>1,812 wt%</em>

I hope it helps!

5 0
2 years ago
What is the three properties of matter
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A solid, a liquid or a gas.
6 0
2 years ago
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Estimate ΔH for the reaction using bond dissociation energies from Table 7.1. Give your answer in kcal. C6H12O6 has five C−C bon
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The equation for the photosynthesis reaction in which carbon dioxide and water react to form glucose is . The hear reaction is the difference between the bond dissociation energies in the products and the bond dissociation energies of the reactants

 

The reactant molecules have 12 C = O, 12 H - O bonds while the product molecules have 5 C - C, 7 C – O, 5 H – O, and 6 O = O bonds. The average bond dissociation energies for the bonds involved in the reaction are 191 for C = O, 112 for H – O, 83 C –C, 99 C – H, 86 C – O, 119 O = O.

 

Substitute the average bond dissociation energies in the equation for and calculate as follows

= [12 (C=O) + 12 (H-O)] – [5(C-C) + 7(C-H) + 7 (C-O) + 5(H-O) + 6(O=O)]

= [12x191 kcal/mol + 12x112 kcal//mol] – [5x83 kcal/mol + 7x99 kcal/mol + 7x86 kcal/mol + 5x112 kcal/mol + 6x119 kcal/mol]

= 3636 kcal/mol – 2984 kcal/mol = 652 kcal/mol x 4.184 Kj/1kcal = 2.73x10^3 kJ/mol

 

So, enthalpy change for the reaction is 652 kcal/mol or 2.73x10^3 kJ/mol

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5 0
3 years ago
A student experimentally determines the density of a metal cube. The edge length of the cube is measured using calipers. The cub
IgorC [24]

Answer:

10.9%.

Explanation:

The first thing to do in order to solve this question is to Determine the value for the volume of the the cube. This can be done by taking the cube root of the length of the cube;

The volume of the cube = (length of the cube)^3 = length × length × length = 1.72 × 1.72 × 1.72 =( 1.72)^3 = 5.09cm^3.

The next thing you do is to Determine the exponential density, the can be done by using the formula below;

The exponential density = mass/ volume = 55. 786/ 5.09 = 10.96 g/cm^3.

Therefore, the percent error = (true density of the cube - exponential density of the cube)÷ true density of the cube × 100.

Hence, the percent error = 12.30 - 10.96/12.30 × 100 = 10.9%.

8 0
2 years ago
A gas with a volume of 4.0L at a pressure of 205 kPa is allowed to expand to a volume of 12000 mL. What is the pressure in atmos
Leni [432]

Answer: The pressure in atmospheres is 0.674 in the container if the temperature remains constant.

Explanation:

Boyle's Law: This law states that pressure is inversely proportional to the volume of the gas at constant temperature and number of moles.

P\propto \frac{1}{V}     (At constant temperature and number of moles)

P_1V_1=P_2V_2  

where,

P_1 = initial pressure of gas  = 205 kPa

P_2 = final pressure of gas = ?

V_1 = initial volume of gas  = 4.0 L

V_2 = final volume of gas = 12000 ml = 12 L    (1L=1000ml)  

205\times 4.0=P_2\times 12  

P_2=68.3kPa=0.674atm        (1kPa=0.0098atm)

Therefore, the pressure in atmospheres is 0.674 in the container if the temperature remains constant.

8 0
3 years ago
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