Answer:
First one: group
Second one: period
Third one: number of valence electrons
Last one: increases
<span>Based on your information 1000 times greater than pH 13 is the best I can come up </span>with.
Answer: a) 
b) 
Explanation:
The reaction is :

Rate = Rate of disappearance of
= Rate of appearance of
Rate =
= ![\frac{d[NO_2]}{4dt}](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BNO_2%5D%7D%7B4dt%7D)
Rate of disappearance of
=
= 
a) Rate of disappearance of
= ![-\frac{d[N_2O_5]}{2dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BN_2O_5%5D%7D%7B2dt%7D)
Rate of appearance of
= ![\frac{d[NO_2]}{4dt}](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BNO_2%5D%7D%7B4dt%7D)
b) Rate of appearance of
= ![\frac{d[NO_2]}{dt}=2\times 1.7\times 10^{-4}}=3.4\times 10^{-4}](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BNO_2%5D%7D%7Bdt%7D%3D2%5Ctimes%201.7%5Ctimes%2010%5E%7B-4%7D%7D%3D3.4%5Ctimes%2010%5E%7B-4%7D)