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3 years ago

Place the following compounds in order of increasing vapor pressure. rubbing alcohol

1 answer:

7 0

Vapor pressure is the pressure which is exerted by the vapors of a liquid in equilibrium with the liquid. Vapor pressure depends on the boiling point; lower the boiling point higher will be the vapor pressure.

Based on the given compounds:

rubbing alcohol is polar and has the strongest intermolecular force of attraction followed by relatively polar ether and finally the non-polar propane.

The increasing order of boiling point will be:

propane < diethyl ether < rubbing alcohol

Thus, the increasing order of vapor pressure will be:

rubbing alcohol < diethyl ether < propane

Ans : F

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At a consent tempture the pressure on a 2.5 l ballon is increased from 2.4 atm to 5.8 atm. what is the new volume?

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Answer:

1.034 L

Explanation:

P1 V1 = P2 V2

P1 V1 / P2 = V2

2.4 (2.5) / 5.8 = V2 = 1.034 L

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1 year ago

The following compound has been found effective in treating pain and inflammation (J. Med Chem. 2007, 4222). Which sequence corr

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<h3><u>Full Question:</u></h3>

The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?

A) 1 < 2 < 3

B) 2 < 3 < 1

C) 3 < 1 < 2

D) 1 < 3 < 2

<h3><u>Answer: </u></h3>

The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.

Option B

<h3><u>Explanation. </u></h3>

Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.

A carbonyl compound is a $sp^2$ hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.

In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.

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3 years ago

7. Disulfur dichloride can be made by reacting chlorine gas with molten sulfur. What is the yield of S2Cl2 expected in a laborat

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Answer:

11.4g of S₂Cl₂ is the expected yield

9.69g of S₂Cl₂ are produced with a 85% yield

Explanation:

The reaction of sulfur S₈ with Cl₂ to produce S₂Cl₂ is:

S₈ + 4Cl₂ → 4S₂Cl₂

<em>Where 1 mole of sulfur reacts with four moles of chlorine to produce four moles of disulfur dichloride.</em>

To find the limiting reactant you need to convert mass of each reactant to moles using its molar mass, thus:

S₈ (Molar mass: 256.52g/mol): 10.0g ₓ (1mol / 256.52g) = 0.0390 moles S₈

Cl₂ (Molar mass: 70.9g/mol): 6.00g ₓ (1mol / 70.9g) = 0.0846 moles Cl₂

For a complete reaction of 0.0390 moles of sulfur, there are necessaries:

0.0390 mol S₈ ₓ (4 mol Cl₂ / 1 mol S₈) = <em>0.156 moles Cl₂. </em>As you have just 0.0846 moles of chlorine, Cl₂ is the limiting reactant.

As 4 moles of Cl₂ produce 4 moles of S₂Cl₂.<em> 0.0846 moles of Cl₂ produce, in theory, 0.0846 moles of S₂Cl₂ (Molar mass: 135.04g/mol). </em>In mass:

0.0846 moles S₂Cl₂ ₓ (135.04g/mol) =

<h3>11.4g of S₂Cl₂ is the expected yield</h3>

If you produce just the 85.0% of yield, mass of S₂Cl₂ is:

11.4g ₓ 85% =

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3 years ago

In Part A, we saw that the theoretical yield of aluminum oxide is 1.60 mol . Calculate the percent yield if the actual yield of

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Taking into account definition of percent yield, the percent yield for the reaction is 76.25%.

<h3>Percent yield</h3>

The percent yield is the ratio of the actual return to the theoretical return expressed as a percentage.

The percent yield is calculated as the experimental yield divided by the theoretical yield multiplied by 100%:

$percent yield=\frac{actual yield}{theorical yield}x100$

where the theoretical yield is the amount of product acquired through the complete conversion of all reagents in the final product, that is, it is the maximum amount of product that could be formed from the given amounts of reagents.

<h3>Percent yield in this case</h3>

In this case, you know: