Answer is: adding NaCl will lower the freezing point of a solution.
A solution (in this example solution of sodium chloride) freezes at a lower temperature than does the pure solvent (deionized water).
The higher the solute concentration (sodium chloride), freezing point depression of the solution will be greater.
Equation describing the change in freezing point:
ΔT = Kf · b · i.
ΔT - temperature change from pure solvent to solution.
Kf - the molal freezing point depression constant.
b - molality (moles of solute per kilogram of solvent).
i - Van’t Hoff Factor.
Dissociation of sodium chloride in water: NaCl(aq) → Na⁺(aq) + Cl⁻(aq).
Answer:

Explanation:
Hello,
In this case, since we can consider hydrogen gas as an ideal gas, we check the volume-pressure-temperature-mole relationship by using the ideal gas equation:

Whereas we are asked to compute the moles given the temperature in Kelvins, thr pressure in atm and volume in L as shown below:

Best regards.
Answer:
for a i think it is choice 2
for b i think it is the first choice
Explanation: