To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
For an object to conduct electricity it should have free or delocalised electrons that are free to pass the charge and hence take part in conducting electricity.
From the given choices
Chlorine is a halogen existing as a diatomic gas. Iodine too is a halogen and 2 Iodine atoms held together by covalent bond. Cl - Cl bonds and I-I bonds are covalent bonds. the outer electrons of Cl and I take part in covalent bonds therefore they are fixed and not free to move about. therefore no free electrons to conduct electricity.
Sulfur is a solid that too is held together by covalent bonds so it does not have free electrons to conduct electricity.
Silver is a metal and a general property of metals are their ability to conduct electricity.
metal structure are metal ions tightly packed together. when the metal atoms are tightly packed their valence electrons are removed and delocalised. Positively charged metal ions are embedded in a sea of delocalised electrons.
therefore there are delocalised electrons that can conduct electricity
answer is 3) silver
The mass of the product is <em>98.78 g.</em>
The word equation is
aluminum + chlorine → product
20.00 g + 98.78 g → <em>x</em> g
If each reactant is completely consumed, the <em>Law of conservation of Mass </em>tells us the mass of the product must be 98.78 g.