The average speed is 75 Km per hour. Remember the equation for speed is Speed = Distance divided by Time
The termination step of the free-radical chlorination of methane is the most stable one among all three steps.
The free-radical substitution reaction between chlorine and methane features three major steps:
Initiation, during which chlorine molecules undergo homolytic fission to produce chlorine free radicals. Ultraviolet radiations are typically applied to supply the energy required for breaking the chlorine-chlorine single bonds. The initiation step is thus <em>endothermic</em>.
Propagation, a process in which chlorine free radicals react with methane molecules and remove a hydrogen atom from the alkane to produce hydrogen chloride and an alkyl radical e.g., . The carbon-containing free radical would react with chlorine molecules to produce chloromethane and yet another chlorine free radical. This process can well repeat itself to chlorinate a significant number of methane molecules.
Termination. Free radicals combine to produce molecules. For example, two chlorine free radicals would combine to produce a chlorine molecule, whereas two alkyl free radicals would combine to produce an alkane with two-carbon atoms in its backbone.
Chemical processes that increase the stability of a substance reduces its chemical potential energy. Energy conserves, thus such processes would also release energy equal to the potential energy lost in quantity. Free radicals are unstable and- as seen in the propagation step- compete readily with neutral molecules for their electrons. The propagation step keeps the number of free radicals constant and is therefore more exothermic than the initiation step. The termination step reduces the number of free radicals, increase the stability of the system by the greatest extent, and is therefore the most exothermic step among the three.
Answer:
The strength of a covalent bond is measured by its bond dissociation energy, that is, the amount of energy required to break that particular bond in a mole of molecules. The enthalpy of a reaction can be estimated based on the energy input required to break bonds and the energy released when new bonds are formed.
Explanation:
Answer:
C. An electron at this electrode has a higher potential energy than it has at a standard hydrogen electrode.
Explanation:
The standard hydrogen electrode (SHE) is used to measure the electrode potential of substances. The standard hydrogen electrode is arbitrarily assigned an electrode potential of zero. Recall that electrode potentials are always measured as reduction potentials in electrochemical systems.
For an electrode that has a negative electrode potential, electrons at this electrode have a higher potential energy compared to electrons at the standard hydrogen electrode. Electrons flow from this electrode to the hydrogen electrode.
On the other hand, a positive electrode potential implies that an electron at this electrode has a lower potential energy than it has at a standard hydrogen electrode. Hence electrons will flow from the standard hydrogen electrode to this electrode.
Answer : The value of is -49.6 kJ/mol
Explanation :
First we have to calculate the reaction quotient.
Reaction quotient (Q) : It is defined as the measurement of the relative amounts of products and reactants present during a reaction at a particular time.
The given balanced chemical reaction is,
The expression for reaction quotient will be :
In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.
Given:
= 5.0 mM
= 0.60 mM
= 5.0 mM
Now put all the given values in this expression, we get
Now we have to calculate the value of .
The formula used for is:
............(1)
where,
= Gibbs free energy for the reaction = ?
= standard Gibbs free energy = -30.5 kJ/mol
R = gas constant =
T = temperature =
Q = reaction quotient =
Now put all the given values in the above formula 1, we get:
Therefore, the value of is -49.6 kJ/mol